Intra- and inter-supramolecular complexation of poly(butyl methacrylate)-co-2-(1,2,3-triazol-4-yl)pyridine copolymers induced by CoII, FeII, and EuIII ions monitored by molecular hydrodynamics methods

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Intra- and inter-supramolecular complexation of poly(butyl methacrylate)-co-2-(1,2,3-triazol-4-yl)pyridine copolymers induced by CoII, FeII, and EuIII ions monitored by molecular hydrodynamics methods. / Pavlov, Georges M.; Perevyazko, Igor; Happ, Bobby; Schubert, Ulrich S.

в: Journal of Polymer Science, Part A: Polymer Chemistry, Том 54, № 16, 15.08.2016, стр. 2632-2639.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{39f155041aac4a7ba2dafc165d19c6f0,

title = "Intra- and inter-supramolecular complexation of poly(butyl methacrylate)-co-2-(1,2,3-triazol-4-yl)pyridine copolymers induced by CoII, FeII, and EuIII ions monitored by molecular hydrodynamics methods",

abstract = "Poly(butyl methacrylate) copolymers embedding bidentate 2-(1,2,3-triazol-4-yl)pyridine (trzpy) chelating units as comonomer in the side chains were synthesized by controlled radical addition-fragmentation transfer (RAFT) polymerization. Intracomplexation and intercomplexation of the macromolecules of the poly(butyl methacrylate) copolymers containing 20 % mol of trzpy units induced by CoII, FeII, and EuIII ions were studied in the solutions by macromolecular hydrodynamics methods. The sedimentation velocity of extremely diluted copolymer solutions and the dynamic viscosity of moderately diluted solutions were studied in a wide range of the salts concentrations. Differences were observed with respect to the copolymer behavior in the presence of the Co2+, Fe2+, Eu3+ ions. These differences are namely due to the differences in the number of coordination bonds required for complex formation and not explicitly to the nature of the corresponding anions.",

keywords = "analytical ultracentrifuge, characterization, crosslinking, gelation, molecular hydrodynamics, supramolecular complexation, viscosity",

author = "Pavlov, {Georges M.} and Igor Perevyazko and Bobby Happ and Schubert, {Ulrich S.}",

year = "2016",

month = aug,

day = "15",

doi = "10.1002/pola.28143",

language = "English",

volume = "54",

pages = "2632--2639",

journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

issn = "0887-624X",

publisher = "Wiley-Blackwell",

number = "16",

}

RIS

TY - JOUR

T1 - Intra- and inter-supramolecular complexation of poly(butyl methacrylate)-co-2-(1,2,3-triazol-4-yl)pyridine copolymers induced by CoII, FeII, and EuIII ions monitored by molecular hydrodynamics methods

AU - Pavlov, Georges M.

AU - Perevyazko, Igor

AU - Happ, Bobby

AU - Schubert, Ulrich S.

PY - 2016/8/15

Y1 - 2016/8/15

N2 - Poly(butyl methacrylate) copolymers embedding bidentate 2-(1,2,3-triazol-4-yl)pyridine (trzpy) chelating units as comonomer in the side chains were synthesized by controlled radical addition-fragmentation transfer (RAFT) polymerization. Intracomplexation and intercomplexation of the macromolecules of the poly(butyl methacrylate) copolymers containing 20 % mol of trzpy units induced by CoII, FeII, and EuIII ions were studied in the solutions by macromolecular hydrodynamics methods. The sedimentation velocity of extremely diluted copolymer solutions and the dynamic viscosity of moderately diluted solutions were studied in a wide range of the salts concentrations. Differences were observed with respect to the copolymer behavior in the presence of the Co2+, Fe2+, Eu3+ ions. These differences are namely due to the differences in the number of coordination bonds required for complex formation and not explicitly to the nature of the corresponding anions.

AB - Poly(butyl methacrylate) copolymers embedding bidentate 2-(1,2,3-triazol-4-yl)pyridine (trzpy) chelating units as comonomer in the side chains were synthesized by controlled radical addition-fragmentation transfer (RAFT) polymerization. Intracomplexation and intercomplexation of the macromolecules of the poly(butyl methacrylate) copolymers containing 20 % mol of trzpy units induced by CoII, FeII, and EuIII ions were studied in the solutions by macromolecular hydrodynamics methods. The sedimentation velocity of extremely diluted copolymer solutions and the dynamic viscosity of moderately diluted solutions were studied in a wide range of the salts concentrations. Differences were observed with respect to the copolymer behavior in the presence of the Co2+, Fe2+, Eu3+ ions. These differences are namely due to the differences in the number of coordination bonds required for complex formation and not explicitly to the nature of the corresponding anions.

KW - analytical ultracentrifuge

KW - characterization

KW - crosslinking

KW - gelation

KW - molecular hydrodynamics

KW - supramolecular complexation

KW - viscosity

UR - http://www.scopus.com/inward/record.url?scp=84977599477&partnerID=8YFLogxK

U2 - 10.1002/pola.28143

DO - 10.1002/pola.28143

M3 - Article

VL - 54

SP - 2632

EP - 2639

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

SN - 0887-624X

IS - 16

ER -

ID: 7604174