Standard

Interrupted amperometry : the new possibilities in electrochemical measurements. / Semenova, Ekaterina; Navolotskaya, Daria; Ermakov, Sergey.

в: Pure and Applied Chemistry, Том 89, № 10, 10.2017, стр. 1459-1469.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Semenova, E, Navolotskaya, D & Ermakov, S 2017, 'Interrupted amperometry: the new possibilities in electrochemical measurements', Pure and Applied Chemistry, Том. 89, № 10, стр. 1459-1469. https://doi.org/10.1515/pac-2017-0302

APA

Semenova, E., Navolotskaya, D., & Ermakov, S. (2017). Interrupted amperometry: the new possibilities in electrochemical measurements. Pure and Applied Chemistry, 89(10), 1459-1469. https://doi.org/10.1515/pac-2017-0302

Vancouver

Semenova E, Navolotskaya D, Ermakov S. Interrupted amperometry: the new possibilities in electrochemical measurements. Pure and Applied Chemistry. 2017 Окт.;89(10):1459-1469. https://doi.org/10.1515/pac-2017-0302

Author

Semenova, Ekaterina ; Navolotskaya, Daria ; Ermakov, Sergey. / Interrupted amperometry : the new possibilities in electrochemical measurements. в: Pure and Applied Chemistry. 2017 ; Том 89, № 10. стр. 1459-1469.

BibTeX

@article{31bddc20169f4f0696d363c0477ae211,
title = "Interrupted amperometry: the new possibilities in electrochemical measurements",
abstract = "Interrupted amperometry is a new highly sensitive method for diffusion current measuring. The main feature of the proposed technique is the use of capacitive current as the analytical signal together with the faradaic current. The conventional electrical circuit for amperometric measurements is complemented by a switcher that enables periodical interruption of the circuit. The technique was successfully applied for direct amperometric determination of lead, cadmium and iron ions, phenol and hydroquinone; for determination of dichromate ion via titration; for determination of dissolved oxygen in water by Clark-type sensor. In all the mentioned cases the achieved values of analytical characteristics are significantly better than for conventional amperometric methods. There are limitations and perspectives of the proposed technique considered.",
keywords = "amperometry, analytical chemistry, aqueous solutions, chemical sensors, electrochemistry, electrodes, heavy metals, iron, Mendeleev XX, oxygen, phenol, sensitivity, trace elements, ANODIC-STRIPPING VOLTAMMETRY, FLOW-INJECTION ANALYSIS, CARBON-PASTE ELECTRODE, PULSE VOLTAMMETRY, POLAROGRAPHY, TRANSFORM, MERCURY, WAVELET, CHROMATOGRAPHY, METHANOL",
author = "Ekaterina Semenova and Daria Navolotskaya and Sergey Ermakov",
year = "2017",
month = oct,
doi = "10.1515/pac-2017-0302",
language = "Английский",
volume = "89",
pages = "1459--1469",
journal = "Pure and Applied Chemistry",
issn = "0033-4545",
publisher = "De Gruyter",
number = "10",

}

RIS

TY - JOUR

T1 - Interrupted amperometry

T2 - the new possibilities in electrochemical measurements

AU - Semenova, Ekaterina

AU - Navolotskaya, Daria

AU - Ermakov, Sergey

PY - 2017/10

Y1 - 2017/10

N2 - Interrupted amperometry is a new highly sensitive method for diffusion current measuring. The main feature of the proposed technique is the use of capacitive current as the analytical signal together with the faradaic current. The conventional electrical circuit for amperometric measurements is complemented by a switcher that enables periodical interruption of the circuit. The technique was successfully applied for direct amperometric determination of lead, cadmium and iron ions, phenol and hydroquinone; for determination of dichromate ion via titration; for determination of dissolved oxygen in water by Clark-type sensor. In all the mentioned cases the achieved values of analytical characteristics are significantly better than for conventional amperometric methods. There are limitations and perspectives of the proposed technique considered.

AB - Interrupted amperometry is a new highly sensitive method for diffusion current measuring. The main feature of the proposed technique is the use of capacitive current as the analytical signal together with the faradaic current. The conventional electrical circuit for amperometric measurements is complemented by a switcher that enables periodical interruption of the circuit. The technique was successfully applied for direct amperometric determination of lead, cadmium and iron ions, phenol and hydroquinone; for determination of dichromate ion via titration; for determination of dissolved oxygen in water by Clark-type sensor. In all the mentioned cases the achieved values of analytical characteristics are significantly better than for conventional amperometric methods. There are limitations and perspectives of the proposed technique considered.

KW - amperometry

KW - analytical chemistry

KW - aqueous solutions

KW - chemical sensors

KW - electrochemistry

KW - electrodes

KW - heavy metals

KW - iron

KW - Mendeleev XX

KW - oxygen

KW - phenol

KW - sensitivity

KW - trace elements

KW - ANODIC-STRIPPING VOLTAMMETRY

KW - FLOW-INJECTION ANALYSIS

KW - CARBON-PASTE ELECTRODE

KW - PULSE VOLTAMMETRY

KW - POLAROGRAPHY

KW - TRANSFORM

KW - MERCURY

KW - WAVELET

KW - CHROMATOGRAPHY

KW - METHANOL

U2 - 10.1515/pac-2017-0302

DO - 10.1515/pac-2017-0302

M3 - статья

VL - 89

SP - 1459

EP - 1469

JO - Pure and Applied Chemistry

JF - Pure and Applied Chemistry

SN - 0033-4545

IS - 10

ER -

ID: 9461444