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Interfacial engineering by creating Cu-based ternary heterostructures on C3N4tubes towards enhanced photocatalytic oxidative coupling of benzylamines. / Fu, Yunqi; Zheng, Mang; Li, Qi; Zhang, Liping; Wang, Shuai; Kondratiev, V. V.; Jiang, Baojiang.

в: RSC Advances, Том 10, № 47, 18.07.2020, стр. 28059-28065.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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Fu, Yunqi ; Zheng, Mang ; Li, Qi ; Zhang, Liping ; Wang, Shuai ; Kondratiev, V. V. ; Jiang, Baojiang. / Interfacial engineering by creating Cu-based ternary heterostructures on C3N4tubes towards enhanced photocatalytic oxidative coupling of benzylamines. в: RSC Advances. 2020 ; Том 10, № 47. стр. 28059-28065.

BibTeX

@article{2f9c14c5a78142c185a6ed69a7c0d143,
title = "Interfacial engineering by creating Cu-based ternary heterostructures on C3N4tubes towards enhanced photocatalytic oxidative coupling of benzylamines",
abstract = "Benzylamine coupling is a very important reaction for the synthesis of imine but still faces many challenges. Herein, we present a highly effective strategy towards the coupling reaction by using environmentally friendly catalysts. These catalysts are composed of Cu/Cu2O/Cu3N heterostructures supported by C3N4 tubes and the composites were synthesized by one-step hydrothermal treatment followed by calcination. Cu2O, Cu3N, and C3N4 all are responsive to visible light and the heterojunction formed can greatly enhance the charge separation. When used as photocatalysts for oxidative self-coupling of benzylamine at a low temperature of 323 K in air, Cu/Cu2O/Cu3N/C3N4 was able to give conversion and selectivity values of up to 99% and 98%, respectively. The high efficiency of the catalysts is attributable to their ability to generate large quantities of free radicals (such as ·OH and ·O2-) under visible-light irradiation. This journal is ",
author = "Yunqi Fu and Mang Zheng and Qi Li and Liping Zhang and Shuai Wang and Kondratiev, {V. V.} and Baojiang Jiang",
note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",
year = "2020",
month = jul,
day = "18",
doi = "10.1039/d0ra03164j",
language = "English",
volume = "10",
pages = "28059--28065",
journal = "RSC Advances",
issn = "2046-2069",
publisher = "Royal Society of Chemistry",
number = "47",

}

RIS

TY - JOUR

T1 - Interfacial engineering by creating Cu-based ternary heterostructures on C3N4tubes towards enhanced photocatalytic oxidative coupling of benzylamines

AU - Fu, Yunqi

AU - Zheng, Mang

AU - Li, Qi

AU - Zhang, Liping

AU - Wang, Shuai

AU - Kondratiev, V. V.

AU - Jiang, Baojiang

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2020/7/18

Y1 - 2020/7/18

N2 - Benzylamine coupling is a very important reaction for the synthesis of imine but still faces many challenges. Herein, we present a highly effective strategy towards the coupling reaction by using environmentally friendly catalysts. These catalysts are composed of Cu/Cu2O/Cu3N heterostructures supported by C3N4 tubes and the composites were synthesized by one-step hydrothermal treatment followed by calcination. Cu2O, Cu3N, and C3N4 all are responsive to visible light and the heterojunction formed can greatly enhance the charge separation. When used as photocatalysts for oxidative self-coupling of benzylamine at a low temperature of 323 K in air, Cu/Cu2O/Cu3N/C3N4 was able to give conversion and selectivity values of up to 99% and 98%, respectively. The high efficiency of the catalysts is attributable to their ability to generate large quantities of free radicals (such as ·OH and ·O2-) under visible-light irradiation. This journal is

AB - Benzylamine coupling is a very important reaction for the synthesis of imine but still faces many challenges. Herein, we present a highly effective strategy towards the coupling reaction by using environmentally friendly catalysts. These catalysts are composed of Cu/Cu2O/Cu3N heterostructures supported by C3N4 tubes and the composites were synthesized by one-step hydrothermal treatment followed by calcination. Cu2O, Cu3N, and C3N4 all are responsive to visible light and the heterojunction formed can greatly enhance the charge separation. When used as photocatalysts for oxidative self-coupling of benzylamine at a low temperature of 323 K in air, Cu/Cu2O/Cu3N/C3N4 was able to give conversion and selectivity values of up to 99% and 98%, respectively. The high efficiency of the catalysts is attributable to their ability to generate large quantities of free radicals (such as ·OH and ·O2-) under visible-light irradiation. This journal is

UR - http://www.scopus.com/inward/record.url?scp=85091700662&partnerID=8YFLogxK

U2 - 10.1039/d0ra03164j

DO - 10.1039/d0ra03164j

M3 - Article

AN - SCOPUS:85091700662

VL - 10

SP - 28059

EP - 28065

JO - RSC Advances

JF - RSC Advances

SN - 2046-2069

IS - 47

ER -

ID: 85824156