Vit105 (Zr_52.5Cu_17.9Ni_14.6Al₁₀Ti₅ at. %) bulk metallic glass samples were processed by high-pressure torsion and accumulative high-pressure torsion. By DSC, XRD and SANS methods it was shown that accumulative high-pressure torsion allows for achieving high real strains and leads to an increase in the free volume and significant transformation of the structure. Minor crystallization was detected after high-pressure torsion processing.