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Hyperfine coupling of the iodine D0+u and β1g ion-pair states. / Батуро, Вера Владимировна; Черепанов, Игорь; Лукашов, Сергей Сергеевич; Петров, Александр Николаевич; Порецкий, Сергей Артемович; Правилов, Анатолий Михайлович.

в: Journal of Physics B: Atomic, Molecular and Optical Physics, Том 51, № 9, 095101, 14.05.2018.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{522d0b5b0a614ccabdc729ff95135228,
title = "Hyperfine coupling of the iodine D0+u and β1g ion-pair states",
abstract = "Detailed studies of I 2(β1 g , v β = 13, J β ∼ v D = 12, J D and D, 48, J D ∼ β, 47, J β) rovibronic state coupling have been carried out using two-step two-color, hν 1 + hν 2 and hν 1 + 2hν 2, optical-optical double resonance excitation schemes, respectively. The hyperfine interaction satisfying the = 0, 1 selection rules (magnetic-dipole interaction) has been observed. No electric-quadrupole hyperfine coupling ( = 2) has been found. The dependences of ratios of luminescence intensities from the rovibronic states populated due to the hyperfine coupling to those from optically populated ones on energy gaps between these states have been experimentally determined. The matrix elements as well as the hyperfine structure constant have been obtained using these dependences. It is shown that they increase slightly with the vibrational quantum number of the states. ",
keywords = "Diatomic molecules, HYPERFINE INTERACTION, iodine molecule ion-pair states, diatomic molecules, hyperfine interaction, iodine molecule ion-pair states, I-2, HOMONUCLEAR DIATOMIC-MOLECULES, OPTICAL DOUBLE-RESONANCE, NONADIABATIC TRANSITIONS, SPECTROSCOPY, PREDISSOCIATION, U-G PERTURBATIONS, B-STATE, SPECTRUM, VALENCE STATES",
author = "Батуро, {Вера Владимировна} and Игорь Черепанов and Лукашов, {Сергей Сергеевич} and Петров, {Александр Николаевич} and Порецкий, {Сергей Артемович} and Правилов, {Анатолий Михайлович}",
note = "Funding Information: The authors acknowledge Saint Petersburg State University for research grant 11.38.249.2014 and Russian Foundation for Basic Researches for research grant 16-03-00225a and Centre for Applied Aerodynamics of Saint Petersburg State University Research park for the manufacture of experimental set-up elements in the framework of project 8459 # 123-8459. The calculations of hyperfine structure of iodine molecule were supported by the grant of Russian Science Foundation #14-31-00022.",
year = "2018",
month = may,
day = "14",
doi = "10.1088/1361-6455/aab6e3",
language = "English",
volume = "51",
journal = "Journal of the European Optical Society Part B: Quantum Optics",
issn = "0953-4075",
publisher = "IOP Publishing Ltd.",
number = "9",

}

RIS

TY - JOUR

T1 - Hyperfine coupling of the iodine D0+u and β1g ion-pair states

AU - Батуро, Вера Владимировна

AU - Черепанов, Игорь

AU - Лукашов, Сергей Сергеевич

AU - Петров, Александр Николаевич

AU - Порецкий, Сергей Артемович

AU - Правилов, Анатолий Михайлович

N1 - Funding Information: The authors acknowledge Saint Petersburg State University for research grant 11.38.249.2014 and Russian Foundation for Basic Researches for research grant 16-03-00225a and Centre for Applied Aerodynamics of Saint Petersburg State University Research park for the manufacture of experimental set-up elements in the framework of project 8459 # 123-8459. The calculations of hyperfine structure of iodine molecule were supported by the grant of Russian Science Foundation #14-31-00022.

PY - 2018/5/14

Y1 - 2018/5/14

N2 - Detailed studies of I 2(β1 g , v β = 13, J β ∼ v D = 12, J D and D, 48, J D ∼ β, 47, J β) rovibronic state coupling have been carried out using two-step two-color, hν 1 + hν 2 and hν 1 + 2hν 2, optical-optical double resonance excitation schemes, respectively. The hyperfine interaction satisfying the = 0, 1 selection rules (magnetic-dipole interaction) has been observed. No electric-quadrupole hyperfine coupling ( = 2) has been found. The dependences of ratios of luminescence intensities from the rovibronic states populated due to the hyperfine coupling to those from optically populated ones on energy gaps between these states have been experimentally determined. The matrix elements as well as the hyperfine structure constant have been obtained using these dependences. It is shown that they increase slightly with the vibrational quantum number of the states.

AB - Detailed studies of I 2(β1 g , v β = 13, J β ∼ v D = 12, J D and D, 48, J D ∼ β, 47, J β) rovibronic state coupling have been carried out using two-step two-color, hν 1 + hν 2 and hν 1 + 2hν 2, optical-optical double resonance excitation schemes, respectively. The hyperfine interaction satisfying the = 0, 1 selection rules (magnetic-dipole interaction) has been observed. No electric-quadrupole hyperfine coupling ( = 2) has been found. The dependences of ratios of luminescence intensities from the rovibronic states populated due to the hyperfine coupling to those from optically populated ones on energy gaps between these states have been experimentally determined. The matrix elements as well as the hyperfine structure constant have been obtained using these dependences. It is shown that they increase slightly with the vibrational quantum number of the states.

KW - Diatomic molecules

KW - HYPERFINE INTERACTION

KW - iodine molecule ion-pair states

KW - diatomic molecules

KW - hyperfine interaction

KW - iodine molecule ion-pair states

KW - I-2

KW - HOMONUCLEAR DIATOMIC-MOLECULES

KW - OPTICAL DOUBLE-RESONANCE

KW - NONADIABATIC TRANSITIONS

KW - SPECTROSCOPY

KW - PREDISSOCIATION

KW - U-G PERTURBATIONS

KW - B-STATE

KW - SPECTRUM

KW - VALENCE STATES

UR - http://www.scopus.com/inward/record.url?scp=85048027046&partnerID=8YFLogxK

UR - http://stacks.iop.org/0953-4075/51/i=9/a=095101?key=crossref.135d20f053915bd8a99f65a3243b1362

UR - http://www.mendeley.com/research/hyperfine-coupling-iodine-boldsymbold0boldsymbolu-i%CE%B2i-1-sub-igi-sub-ionpair-states

U2 - 10.1088/1361-6455/aab6e3

DO - 10.1088/1361-6455/aab6e3

M3 - Article

VL - 51

JO - Journal of the European Optical Society Part B: Quantum Optics

JF - Journal of the European Optical Society Part B: Quantum Optics

SN - 0953-4075

IS - 9

M1 - 095101

ER -

ID: 33813538