Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Hydrodynamic size of complexes of holmium and dysprosium with schiff bases and various counterions in solutions. / Lavrenko, P. N.; Evlampieva, N. P.; Barabanov, V. P.; Galyametdinov, Yu G.
в: Russian Journal of Physical Chemistry A, Том 79, № 3, 03.2005, стр. 408-414.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Hydrodynamic size of complexes of holmium and dysprosium with schiff bases and various counterions in solutions
AU - Lavrenko, P. N.
AU - Evlampieva, N. P.
AU - Barabanov, V. P.
AU - Galyametdinov, Yu G.
PY - 2005/3
Y1 - 2005/3
N2 - Diffusional-viscosimetric analysis of liquid crystal metallocomplexes of holmium and dysprosium with 4-alkoxy-N-alkyl-2-hydroxybenzaldiimines in the protonated (zwitterionic) form and various counterions demonstrated that the complexes of the lanthanides with perfluoroalkylsulfate anions have hydrodynamic sizes half those of the complexes with nitrate anions, with the type of lanthanide having virtually no effect on the size of the complex. The results correlate with the geometric size of the ligand and the parameters of the mesophase and crystal lattice of the complex.
AB - Diffusional-viscosimetric analysis of liquid crystal metallocomplexes of holmium and dysprosium with 4-alkoxy-N-alkyl-2-hydroxybenzaldiimines in the protonated (zwitterionic) form and various counterions demonstrated that the complexes of the lanthanides with perfluoroalkylsulfate anions have hydrodynamic sizes half those of the complexes with nitrate anions, with the type of lanthanide having virtually no effect on the size of the complex. The results correlate with the geometric size of the ligand and the parameters of the mesophase and crystal lattice of the complex.
UR - http://www.scopus.com/inward/record.url?scp=14644397245&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:14644397245
VL - 79
SP - 408
EP - 414
JO - Russian Journal of Physical Chemistry A
JF - Russian Journal of Physical Chemistry A
SN - 0036-0244
IS - 3
ER -
ID: 90458104