Результаты исследований: Научные публикации в периодических изданиях › статья
Hybrid One-Dimensional 15-Crown-5-ether-uranyl-selenate Polymers in [K@(C10H20O5)][(UO2)(SeO4)(HSeO4)(H2O)]: Synthesis and Characterization. / Gurzhiy, V.V.; Tyumentseva, O.S.; Krivovichev, S.V.; Tananaev, I.G.
в: Zeitschrift fur Anorganische und Allgemeine Chemie, Том 641, № 6, 2015, стр. 1110-1113.Результаты исследований: Научные публикации в периодических изданиях › статья
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TY - JOUR
T1 - Hybrid One-Dimensional 15-Crown-5-ether-uranyl-selenate Polymers in [K@(C10H20O5)][(UO2)(SeO4)(HSeO4)(H2O)]: Synthesis and Characterization
AU - Gurzhiy, V.V.
AU - Tyumentseva, O.S.
AU - Krivovichev, S.V.
AU - Tananaev, I.G.
PY - 2015
Y1 - 2015
N2 - Copyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.The hybrid organic-inorganic uranyl selenate, [K@(C10H20O5)][(UO2)(SeO4)(HSeO4)(H2O)] (I), was prepared by isothermal evaporation from aqueous solutions. The crystal structure of I [orthorhombic, Pnma, a = 15.386(3), b = 10.771(2), c = 13.239(3) Å, V = 2194.0(7) Å3, Z = 4, R1 = 0.042] is based upon complex 15-crown-5-ether-uranyl-selenate polymeric units consisting of uranyl selenate chains decorated by [K@(15-crown-5)]+ complexes via strong ionic K+-O bonds. The 1D hybrid units are packed in a parquetted-like fashion and connected to each other by hydrogen bonds and residual van der Waals interactions.
AB - Copyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.The hybrid organic-inorganic uranyl selenate, [K@(C10H20O5)][(UO2)(SeO4)(HSeO4)(H2O)] (I), was prepared by isothermal evaporation from aqueous solutions. The crystal structure of I [orthorhombic, Pnma, a = 15.386(3), b = 10.771(2), c = 13.239(3) Å, V = 2194.0(7) Å3, Z = 4, R1 = 0.042] is based upon complex 15-crown-5-ether-uranyl-selenate polymeric units consisting of uranyl selenate chains decorated by [K@(15-crown-5)]+ complexes via strong ionic K+-O bonds. The 1D hybrid units are packed in a parquetted-like fashion and connected to each other by hydrogen bonds and residual van der Waals interactions.
U2 - 10.1002/zaac.201500208
DO - 10.1002/zaac.201500208
M3 - Article
VL - 641
SP - 1110
EP - 1113
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
SN - 0044-2313
IS - 6
ER -
ID: 3933078