Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
The phosphonium-decorated phenanthro-imidazolyl pyridine ligand, LP+Br, readily reacts with zinc(II) and cadmium(II) bromides to give inorganic-organic zero-dimensional compounds [LP+ZnBr2]2[ZnBr4] (1) and [(LP+)2Cd2Br4][CdBr4] (2), respectively, upon crystallization. These salts are moderately fluorescent in the solid state under ambient conditions (λem = 458 nm, φem = 0.11 for 1; λem = 460 nm, φem = 0.13 for 2). Their emission results from spin-allowed electronic transitions localized on the organic component with the negligible effect of [MBr4]2- and MBr2 units. Contrary to ionic species 1 and 2, lead(II) bromide affords a neutral and water-stable complex [(LP+)2Pb3Br8] (3), showing weak room-temperature phosphorescence arising from spin-orbit coupling due to the heavy atom effect. The emission, which is substantially enhanced for the amorphous sample of 3 (λem = 575 nm, φem = 0.06), is assigned to the intraligand triplet excited state, which is a rare phenomenon among Pb(II) molecular materials.
Язык оригинала | английский |
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Страницы (с-по) | 19220-19231 |
Число страниц | 12 |
Журнал | Inorganic Chemistry |
Том | 61 |
Номер выпуска | 48 |
Дата раннего онлайн-доступа | 22 ноя 2022 |
DOI | |
Состояние | Опубликовано - 5 дек 2022 |
ID: 100603767