High-pressure synthesis of α-PbO2 and its crystal structure at 293, 203, and 113 K from single crystal diffraction data

Standard

High-pressure synthesis of α-PbO₂ and its crystal structure at 293, 203, and 113 K from single crystal diffraction data. / Filatov, Stanislav; Bendeliani, Nikolay; Albert, Barbara; Kopf, Jürgen; Dyuzeva, Tatiana; Lityagina, Ludmila.

в: Solid State Sciences, Том 7, № 11, 01.11.2005, стр. 1363-1368.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Author

Filatov, Stanislav ; Bendeliani, Nikolay ; Albert, Barbara ; Kopf, Jürgen ; Dyuzeva, Tatiana ; Lityagina, Ludmila. / High-pressure synthesis of α-PbO₂ and its crystal structure at 293, 203, and 113 K from single crystal diffraction data. в: Solid State Sciences. 2005 ; Том 7, № 11. стр. 1363-1368.

BibTeX

@article{04f60bd33a0a477fb29289b47c8c03b3,

title = "High-pressure synthesis of α-PbO2 and its crystal structure at 293, 203, and 113 K from single crystal diffraction data",

abstract = "The synthesis and the first single crystal structure refinements of α-PbO2, a high-pressure modification of lead dioxide, at room and low temperatures are presented (RFsigma/RFuniq 0.025/0.048, 0.028/0.047, 0.027/0.044, wRFsigma/wRFuniq 0.056/0.061, 0.059/0.063, 0.059/0.062 at 293, 203, and 113 K, correspondingly). Single crystals were grown by a hydrothermal synthesis procedure (p=4.0 GPa, temperature range 600-300 °C, cooling rate 1.25°/min). α-PbO2 is orthorhombic, space group Pbcn (No. 60), Z=4, with a=4.9858(2) {\AA}, b=5.9596(3) {\AA}, c=5.4626(2) {\AA}, V=162.31(1) {\AA}3 for T=293 K. The description of the structure is given from a cation- and an anion-centered perspective. The oxygen atoms are coordinated by three lead atoms and oscillate mainly perpendicularly to the Pb 3-plane. The principal axes of the thermal displacement parameters decrease under cooling, and the anisotropy of the thermal oscillations increases from 293 to 113 K. Anisotropic thermal expansion was observed. Upon heating, the crystal structure extends practically only along the a-axis.",

keywords = "α-PbO, Crystal structure, Low temperature, Single crystal X-ray analysis, Thermal expansion",

author = "Stanislav Filatov and Nikolay Bendeliani and Barbara Albert and J{\"u}rgen Kopf and Tatiana Dyuzeva and Ludmila Lityagina",

year = "2005",

month = nov,

day = "1",

doi = "10.1016/j.solidstatesciences.2005.08.007",

language = "English",

volume = "7",

pages = "1363--1368",

journal = "Solid State Sciences",

issn = "1293-2558",

publisher = "Elsevier",

number = "11",

}

RIS

TY - JOUR

T1 - High-pressure synthesis of α-PbO2 and its crystal structure at 293, 203, and 113 K from single crystal diffraction data

AU - Filatov, Stanislav

AU - Bendeliani, Nikolay

AU - Albert, Barbara

AU - Kopf, Jürgen

AU - Dyuzeva, Tatiana

AU - Lityagina, Ludmila

PY - 2005/11/1

Y1 - 2005/11/1

N2 - The synthesis and the first single crystal structure refinements of α-PbO2, a high-pressure modification of lead dioxide, at room and low temperatures are presented (RFsigma/RFuniq 0.025/0.048, 0.028/0.047, 0.027/0.044, wRFsigma/wRFuniq 0.056/0.061, 0.059/0.063, 0.059/0.062 at 293, 203, and 113 K, correspondingly). Single crystals were grown by a hydrothermal synthesis procedure (p=4.0 GPa, temperature range 600-300 °C, cooling rate 1.25°/min). α-PbO2 is orthorhombic, space group Pbcn (No. 60), Z=4, with a=4.9858(2) Å, b=5.9596(3) Å, c=5.4626(2) Å, V=162.31(1) Å3 for T=293 K. The description of the structure is given from a cation- and an anion-centered perspective. The oxygen atoms are coordinated by three lead atoms and oscillate mainly perpendicularly to the Pb 3-plane. The principal axes of the thermal displacement parameters decrease under cooling, and the anisotropy of the thermal oscillations increases from 293 to 113 K. Anisotropic thermal expansion was observed. Upon heating, the crystal structure extends practically only along the a-axis.

AB - The synthesis and the first single crystal structure refinements of α-PbO2, a high-pressure modification of lead dioxide, at room and low temperatures are presented (RFsigma/RFuniq 0.025/0.048, 0.028/0.047, 0.027/0.044, wRFsigma/wRFuniq 0.056/0.061, 0.059/0.063, 0.059/0.062 at 293, 203, and 113 K, correspondingly). Single crystals were grown by a hydrothermal synthesis procedure (p=4.0 GPa, temperature range 600-300 °C, cooling rate 1.25°/min). α-PbO2 is orthorhombic, space group Pbcn (No. 60), Z=4, with a=4.9858(2) Å, b=5.9596(3) Å, c=5.4626(2) Å, V=162.31(1) Å3 for T=293 K. The description of the structure is given from a cation- and an anion-centered perspective. The oxygen atoms are coordinated by three lead atoms and oscillate mainly perpendicularly to the Pb 3-plane. The principal axes of the thermal displacement parameters decrease under cooling, and the anisotropy of the thermal oscillations increases from 293 to 113 K. Anisotropic thermal expansion was observed. Upon heating, the crystal structure extends practically only along the a-axis.

KW - α-PbO

KW - Crystal structure

KW - Low temperature

KW - Single crystal X-ray analysis

KW - Thermal expansion

UR - http://www.scopus.com/inward/record.url?scp=27744502710&partnerID=8YFLogxK

U2 - 10.1016/j.solidstatesciences.2005.08.007

DO - 10.1016/j.solidstatesciences.2005.08.007

M3 - Article

AN - SCOPUS:27744502710

VL - 7

SP - 1363

EP - 1368

JO - Solid State Sciences

JF - Solid State Sciences

SN - 1293-2558

IS - 11

ER -

ID: 53953590