DOI

The shape of the vibration-rotation ν(HF) band is studied in HF/Xe and HF/CO mixtures at increasing Xe (or CO) density from gaseous to liquid phase at 293 K. The evolution of the ν(HF) band is determined by coexistence of ensembles of free and complexed molecules. The band of free HF molecules is calculated using the super-Lorentzian profile for rotational HF lines. The νHF bands of the Xe... HF, OC...HF and CO... HF complexes, which appear in the absorption region of P(1) and P(1)-P(4) rotational lines of HF, are formed by superposition of the vibration-rotation bands due to hot transitions from excited levels of the low-frequency intermolecular modes. The νHF bands in the complexes experience a low-frequency shift and become more symmetric with increasing density. A model taking into account spectral exchange between overlapping lines provides correct description of the complex band shape evolution with increasing density.

Язык оригиналаанглийский
Название основной публикации12TH SYMPOSIUM AND SCHOOL ON HIGH-RESOLUTION MOLECULAR SPECTROSCOPY
РедакторыLN Sinitsa, YN Ponomarev, Perevalov
ИздательSPIE
Страницы250-254
Число страниц5
ISBN (печатное издание)0-8194-2505-2
DOI
СостояниеОпубликовано - 1 дек 1997
Событие12th Symposium and School on High-Resolution Molecular Spectroscopy - St. Petersburg, Российская Федерация
Продолжительность: 1 июл 19961 июл 1996

Серия публикаций

НазваниеPROCEEDINGS OF THE SOCIETY OF PHOTO-OPTICAL INSTRUMENTATION ENGINEERS (SPIE)
ИздательSPIE - INT SOC OPTICAL ENGINEERING
Том3090

конференция

конференция12th Symposium and School on High-Resolution Molecular Spectroscopy
Страна/TерриторияРоссийская Федерация
ГородSt. Petersburg
Период1/07/961/07/96

    Предметные области Scopus

  • Электроника, оптика и магнитные материалы
  • Физика конденсатов
  • Прикладные компьютерные науки
  • Прикладная математика
  • Электротехника и электроника

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