Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Thermal effects of the decomposition of potassium, calcium, and strontium amidoboranes at 354, 421, and 483 K are determined via drop calorimetry. The processes of decomposition are weakly exothermic and accompanied by the evolution of hydrogen. Upon the decomposition of calcium amidoborane at 421 K, a prolonged exothermic process is first observed; it is then followed by an endothermic effect, due possibly to the slow structural rearrangement of the product of decomposition. The solid products of decomposition are characterized by solid-state 11В NMR, FTIR spectroscopy, and mass spectrometry.
Язык оригинала | английский |
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Страницы (с-по) | 640-645 |
Число страниц | 6 |
Журнал | Russian Journal of Physical Chemistry A |
Том | 92 |
Номер выпуска | 4 |
DOI | |
Состояние | Опубликовано - 1 апр 2018 |
ID: 34776423