TY - JOUR

T1 - Halogen bonding-assisted assembly of bromoantimonate(V) and polybromide-bromoantimonate-based frameworks

AU - Adonin, Sergey A.

AU - Bondarenko, Mikhail A.

AU - Novikov, Alexander S.

AU - Abramov, Pavel A.

AU - Plyusnin, Pavel E.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

PY - 2019

Y1 - 2019

N2 - In the reactions between the mononuclear [SbBr 6 ] 3- species, Br 2 and various {cationBr} salts, Sb(iii) is commonly oxidized to Sb(v), and the cations play a key role in the formation of the particular bromoantimonate or polybromide-bromoantimonate frameworks of different dimensionalities (1D, 2D or even 3D). Screening this system yielded eleven novel compounds belonging to both the known and the novel structural types. The role of Br⋯Br halogen bonding was studied by DFT calculations, resulting in the estimation of its bond energy (1.1-2.9 kcal mol -1 ).

AB - In the reactions between the mononuclear [SbBr 6 ] 3- species, Br 2 and various {cationBr} salts, Sb(iii) is commonly oxidized to Sb(v), and the cations play a key role in the formation of the particular bromoantimonate or polybromide-bromoantimonate frameworks of different dimensionalities (1D, 2D or even 3D). Screening this system yielded eleven novel compounds belonging to both the known and the novel structural types. The role of Br⋯Br halogen bonding was studied by DFT calculations, resulting in the estimation of its bond energy (1.1-2.9 kcal mol -1 ).

KW - ANIONS

KW - BROMINE

KW - CENTERS

KW - COMPLEXES

KW - CRYSTAL-STRUCTURE

KW - IODIDE

KW - NETWORK

KW - NONABROMOANTIMONATE(V)

KW - NONCOVALENT INTERACTIONS

UR - https://pubs.rsc.org/en/Content/ArticleLanding/2019/CE/C8CE01944D#!divAbstract

UR - http://www.scopus.com/inward/record.url?scp=85060811692&partnerID=8YFLogxK

UR - https://www.elibrary.ru/item.asp?id=38654267

U2 - 10.1039/C8CE01944D

DO - 10.1039/C8CE01944D

M3 - Article

VL - 21

SP - 850

EP - 856

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 5

ER -