Standard

Halogen bonding promotes ferromagnetic exchange in nitronyl nitroxide radicals: a quantitative analysis. / Kudryavtseva, E. N.; Nizamov, R. R.; Tretyakov, E. V.; Gomila, Rosa M.; Frontera, Antonio; Dmitriev, A. A.; Gritsan, N.P.; Nasyrova, D. I.; Efimov, N. N.; Petunin, P.V.; Postnikov, Pavel S.; Romanenko, Gleb; Кукушкин, Вадим Юрьевич.

в: Materials Chemistry and Physics, Том 332, 130252, 15.02.2025.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Kudryavtseva, EN, Nizamov, RR, Tretyakov, EV, Gomila, RM, Frontera, A, Dmitriev, AA, Gritsan, NP, Nasyrova, DI, Efimov, NN, Petunin, PV, Postnikov, PS, Romanenko, G & Кукушкин, ВЮ 2025, 'Halogen bonding promotes ferromagnetic exchange in nitronyl nitroxide radicals: a quantitative analysis', Materials Chemistry and Physics, Том. 332, 130252. https://doi.org/10.1016/j.matchemphys.2024.130252

APA

Kudryavtseva, E. N., Nizamov, R. R., Tretyakov, E. V., Gomila, R. M., Frontera, A., Dmitriev, A. A., Gritsan, N. P., Nasyrova, D. I., Efimov, N. N., Petunin, P. V., Postnikov, P. S., Romanenko, G., & Кукушкин, В. Ю. (2025). Halogen bonding promotes ferromagnetic exchange in nitronyl nitroxide radicals: a quantitative analysis. Materials Chemistry and Physics, 332, [130252]. https://doi.org/10.1016/j.matchemphys.2024.130252

Vancouver

Kudryavtseva EN, Nizamov RR, Tretyakov EV, Gomila RM, Frontera A, Dmitriev AA и пр. Halogen bonding promotes ferromagnetic exchange in nitronyl nitroxide radicals: a quantitative analysis. Materials Chemistry and Physics. 2025 Февр. 15;332. 130252. https://doi.org/10.1016/j.matchemphys.2024.130252

Author

Kudryavtseva, E. N. ; Nizamov, R. R. ; Tretyakov, E. V. ; Gomila, Rosa M. ; Frontera, Antonio ; Dmitriev, A. A. ; Gritsan, N.P. ; Nasyrova, D. I. ; Efimov, N. N. ; Petunin, P.V. ; Postnikov, Pavel S. ; Romanenko, Gleb ; Кукушкин, Вадим Юрьевич. / Halogen bonding promotes ferromagnetic exchange in nitronyl nitroxide radicals: a quantitative analysis. в: Materials Chemistry and Physics. 2025 ; Том 332.

BibTeX

@article{6cc802c8bf1643c29fae9308fcf12c08,
title = "Halogen bonding promotes ferromagnetic exchange in nitronyl nitroxide radicals: a quantitative analysis",
abstract = "Organic nitroxide radicals – specifically chloro-, bromo, and iodo-substituted nitronyl nitroxides – exhibit self-assembly in crystalline states through the combined action of halogen (Hal···ONO) and hydrogen (ONO⋯HMe) bonds. Theoretical calculations reveal that halogen bonds primarily govern the association of these nitroxides. This halogen bonding facilitates the proximity of atoms carrying spin densities of opposite signs, thereby promoting ferromagnetic intermolecular exchange interactions. This research demonstrates, for the first time, that halogen bonding can establish channels facilitating ferromagnetic intermolecular exchange between paramagnetic centers in organic nitronyl nitroxide radicals. This breakthrough discovery expands the potential applications of halogen bonding in the supramolecular modulation of magnetic properties within high-spin clusters—a function that was previously attributed exclusively to hydrogen bonding.",
author = "Kudryavtseva, {E. N.} and Nizamov, {R. R.} and Tretyakov, {E. V.} and Gomila, {Rosa M.} and Antonio Frontera and Dmitriev, {A. A.} and N.P. Gritsan and Nasyrova, {D. I.} and Efimov, {N. N.} and P.V. Petunin and Postnikov, {Pavel S.} and Gleb Romanenko and Кукушкин, {Вадим Юрьевич}",
year = "2025",
month = feb,
day = "15",
doi = "10.1016/j.matchemphys.2024.130252",
language = "English",
volume = "332",
journal = "Materials Chemistry and Physics",
issn = "0254-0584",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Halogen bonding promotes ferromagnetic exchange in nitronyl nitroxide radicals: a quantitative analysis

AU - Kudryavtseva, E. N.

AU - Nizamov, R. R.

AU - Tretyakov, E. V.

AU - Gomila, Rosa M.

AU - Frontera, Antonio

AU - Dmitriev, A. A.

AU - Gritsan, N.P.

AU - Nasyrova, D. I.

AU - Efimov, N. N.

AU - Petunin, P.V.

AU - Postnikov, Pavel S.

AU - Romanenko, Gleb

AU - Кукушкин, Вадим Юрьевич

PY - 2025/2/15

Y1 - 2025/2/15

N2 - Organic nitroxide radicals – specifically chloro-, bromo, and iodo-substituted nitronyl nitroxides – exhibit self-assembly in crystalline states through the combined action of halogen (Hal···ONO) and hydrogen (ONO⋯HMe) bonds. Theoretical calculations reveal that halogen bonds primarily govern the association of these nitroxides. This halogen bonding facilitates the proximity of atoms carrying spin densities of opposite signs, thereby promoting ferromagnetic intermolecular exchange interactions. This research demonstrates, for the first time, that halogen bonding can establish channels facilitating ferromagnetic intermolecular exchange between paramagnetic centers in organic nitronyl nitroxide radicals. This breakthrough discovery expands the potential applications of halogen bonding in the supramolecular modulation of magnetic properties within high-spin clusters—a function that was previously attributed exclusively to hydrogen bonding.

AB - Organic nitroxide radicals – specifically chloro-, bromo, and iodo-substituted nitronyl nitroxides – exhibit self-assembly in crystalline states through the combined action of halogen (Hal···ONO) and hydrogen (ONO⋯HMe) bonds. Theoretical calculations reveal that halogen bonds primarily govern the association of these nitroxides. This halogen bonding facilitates the proximity of atoms carrying spin densities of opposite signs, thereby promoting ferromagnetic intermolecular exchange interactions. This research demonstrates, for the first time, that halogen bonding can establish channels facilitating ferromagnetic intermolecular exchange between paramagnetic centers in organic nitronyl nitroxide radicals. This breakthrough discovery expands the potential applications of halogen bonding in the supramolecular modulation of magnetic properties within high-spin clusters—a function that was previously attributed exclusively to hydrogen bonding.

UR - https://www.mendeley.com/catalogue/f4e3d0b9-b8fc-3fe1-b245-28c702196e43/

U2 - 10.1016/j.matchemphys.2024.130252

DO - 10.1016/j.matchemphys.2024.130252

M3 - Article

VL - 332

JO - Materials Chemistry and Physics

JF - Materials Chemistry and Physics

SN - 0254-0584

M1 - 130252

ER -

ID: 142789100