DOI

A single-crystal X-ray diffraction (XRD) study of diaryliodonium tetrachloroaurates (or, in the recent terminology, tetrachloridoaurates), [(p-XC 6H 4) 2I][AuCl 4] (X = Cl, 1; Br, 2), was performed for 1 (the structure is denoted as 1a to show similarity with the isomorphic structure 2a) and two polymorphs-2a (obtained from MeOH) and 2b (from 1,2-C 2H 4Cl 2). Examination of the XRD data for these three structures revealed 2-center C-X···Au III(X = Cl and Br) and 3-center bifurcated C-Br···(Cl-Au) halogen bonding (abbreviated as XB) between the p-Cl or p-Br atoms of the diaryliodonium cations and the gold(III) atom of [AuCl 4] -. The noncovalent nature of Au III-involving interactions, the nucleophilicity of the gold(III) atoms, and the electrophilic role of p-X atoms of the diaryliodonium cations in the XBs were studied by a set of complementary computational methods. Combined experimental and theoretical studies allowed the recognition of the d-nucleophilicity of the [d 8Au III] atom which, regardless of its rather substantial formal 3+ charge, can function as a d-nucleophilic partner of XB. This conclusion was also supported by theoretical calculations performed for the structures' refcodes BINXOM and ICSD 62511; the obtained data verified the nucleophilicity of Au IIItoward a K +ions or a σ-(Cl)-hole, respectively. All our results, together with consideration of relevant literature, indicate that gold atoms in the three oxidation states (0, I, and even III) exhibit nucleophilicity in XBs.

Язык оригиналаанглийский
Страницы (с-по)15398–15407
Число страниц10
ЖурналInorganic Chemistry
Том61
Номер выпуска39
DOI
СостояниеОпубликовано - 3 окт 2022

    Предметные области Scopus

  • Физическая и теоретическая химия
  • Неорганическая химия

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