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Half-sandwich Ru(II)-thioamide complexes as catalysts for one pot synthesis of aromatic 1,5-diketones. / Rajasekaran, Haritha; Jerome, Peter; Eliseenkov, Eugene V.; Boyarskiy, Vadim P.; Bhuvanesh, Nattamai; Karvembu, Ramasamy.

в: Journal of Organometallic Chemistry, Том 965-966, 122322, 01.05.2022, стр. 122322.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Rajasekaran, H, Jerome, P, Eliseenkov, EV, Boyarskiy, VP, Bhuvanesh, N & Karvembu, R 2022, 'Half-sandwich Ru(II)-thioamide complexes as catalysts for one pot synthesis of aromatic 1,5-diketones', Journal of Organometallic Chemistry, Том. 965-966, 122322, стр. 122322. https://doi.org/10.1016/j.jorganchem.2022.122322

APA

Rajasekaran, H., Jerome, P., Eliseenkov, E. V., Boyarskiy, V. P., Bhuvanesh, N., & Karvembu, R. (2022). Half-sandwich Ru(II)-thioamide complexes as catalysts for one pot synthesis of aromatic 1,5-diketones. Journal of Organometallic Chemistry, 965-966, 122322. [122322]. https://doi.org/10.1016/j.jorganchem.2022.122322

Vancouver

Rajasekaran H, Jerome P, Eliseenkov EV, Boyarskiy VP, Bhuvanesh N, Karvembu R. Half-sandwich Ru(II)-thioamide complexes as catalysts for one pot synthesis of aromatic 1,5-diketones. Journal of Organometallic Chemistry. 2022 Май 1;965-966:122322. 122322. https://doi.org/10.1016/j.jorganchem.2022.122322

Author

Rajasekaran, Haritha ; Jerome, Peter ; Eliseenkov, Eugene V. ; Boyarskiy, Vadim P. ; Bhuvanesh, Nattamai ; Karvembu, Ramasamy. / Half-sandwich Ru(II)-thioamide complexes as catalysts for one pot synthesis of aromatic 1,5-diketones. в: Journal of Organometallic Chemistry. 2022 ; Том 965-966. стр. 122322.

BibTeX

@article{9baa1ae32daa45d5947e850cb6107389,
title = "Half-sandwich Ru(II)-thioamide complexes as catalysts for one pot synthesis of aromatic 1,5-diketones",
abstract = "Four Ru(II)-arene thioamide complexes of the type [(η6-cymene)Ru(PPh3)(L)]+ (L = bidentate monoanionic thioamide ligand) have been synthesized and isolated as their hexafluorophosphate salts. All these complexes are fully characterized by spectroscopic methods. Molecular structures of the ligands (HL2 and HL3) and complex (3) were determined by single crystal X-ray crystallography. The ligands coordinated to Ru center through phenolic O and thioamide S atoms. All the four complexes were tested as catalysts in the one pot synthesis of 1,5-diketones from aromatic ketones and alcohols in the presence of KOtBu, and the products were analyzed by GC/GC–MS/1H NMR. Complexes 1 and 2 behaved as catalysts to produce 1,5-diketones while complexes 3 and 4 catalyzed the reactions to form alkylated ketones. Scope of the reaction was extended to various substituted alcohols and ketones to prepare 1,5-diketones with catalyst 1.",
keywords = "Ru(II)-arene, Half-sandwich, Thioamide, 1,5-diketones, Catalysis",
author = "Haritha Rajasekaran and Peter Jerome and Eliseenkov, {Eugene V.} and Boyarskiy, {Vadim P.} and Nattamai Bhuvanesh and Ramasamy Karvembu",
note = "Publisher Copyright: {\textcopyright} 2022",
year = "2022",
month = may,
day = "1",
doi = "10.1016/j.jorganchem.2022.122322",
language = "English",
volume = "965-966",
pages = "122322",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Half-sandwich Ru(II)-thioamide complexes as catalysts for one pot synthesis of aromatic 1,5-diketones

AU - Rajasekaran, Haritha

AU - Jerome, Peter

AU - Eliseenkov, Eugene V.

AU - Boyarskiy, Vadim P.

AU - Bhuvanesh, Nattamai

AU - Karvembu, Ramasamy

N1 - Publisher Copyright: © 2022

PY - 2022/5/1

Y1 - 2022/5/1

N2 - Four Ru(II)-arene thioamide complexes of the type [(η6-cymene)Ru(PPh3)(L)]+ (L = bidentate monoanionic thioamide ligand) have been synthesized and isolated as their hexafluorophosphate salts. All these complexes are fully characterized by spectroscopic methods. Molecular structures of the ligands (HL2 and HL3) and complex (3) were determined by single crystal X-ray crystallography. The ligands coordinated to Ru center through phenolic O and thioamide S atoms. All the four complexes were tested as catalysts in the one pot synthesis of 1,5-diketones from aromatic ketones and alcohols in the presence of KOtBu, and the products were analyzed by GC/GC–MS/1H NMR. Complexes 1 and 2 behaved as catalysts to produce 1,5-diketones while complexes 3 and 4 catalyzed the reactions to form alkylated ketones. Scope of the reaction was extended to various substituted alcohols and ketones to prepare 1,5-diketones with catalyst 1.

AB - Four Ru(II)-arene thioamide complexes of the type [(η6-cymene)Ru(PPh3)(L)]+ (L = bidentate monoanionic thioamide ligand) have been synthesized and isolated as their hexafluorophosphate salts. All these complexes are fully characterized by spectroscopic methods. Molecular structures of the ligands (HL2 and HL3) and complex (3) were determined by single crystal X-ray crystallography. The ligands coordinated to Ru center through phenolic O and thioamide S atoms. All the four complexes were tested as catalysts in the one pot synthesis of 1,5-diketones from aromatic ketones and alcohols in the presence of KOtBu, and the products were analyzed by GC/GC–MS/1H NMR. Complexes 1 and 2 behaved as catalysts to produce 1,5-diketones while complexes 3 and 4 catalyzed the reactions to form alkylated ketones. Scope of the reaction was extended to various substituted alcohols and ketones to prepare 1,5-diketones with catalyst 1.

KW - Ru(II)-arene

KW - Half-sandwich

KW - Thioamide

KW - 1,5-diketones

KW - Catalysis

UR - http://www.scopus.com/inward/record.url?scp=85126888445&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2022.122322

DO - 10.1016/j.jorganchem.2022.122322

M3 - Article

VL - 965-966

SP - 122322

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

M1 - 122322

ER -

ID: 98858229