The development of environmentally friendly methods of analytical chemistry has been one of the dominant areas of scientific research in recent decades. Environmental performance indices have become a valuable tool for assessing and quantifying the environmental impact of performing chemical analysis. This review article considers the main environmental indices presented in the literature, including aspects such as the safety of used chemical reagents, analytical performance, energy consumption, and waste generation. The review reflects recent advances in green indices and their potential role in a transition to greener and more sustainable analytical practices.