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Gold(I)-Catalyzed Oxidation of Acyl Acetylenes to Vicinal Tricarbonyls. / Dubovtsev, Alexey Yu; Dar'In, Dmitry V.; Kukushkin, Vadim Yu.

в: Organic Letters, Том 21, № 11, 07.06.2019, стр. 4116-4119.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Dubovtsev, AY, Dar'In, DV & Kukushkin, VY 2019, 'Gold(I)-Catalyzed Oxidation of Acyl Acetylenes to Vicinal Tricarbonyls', Organic Letters, Том. 21, № 11, стр. 4116-4119. https://doi.org/10.1021/acs.orglett.9b01297

APA

Dubovtsev, A. Y., Dar'In, D. V., & Kukushkin, V. Y. (2019). Gold(I)-Catalyzed Oxidation of Acyl Acetylenes to Vicinal Tricarbonyls. Organic Letters, 21(11), 4116-4119. https://doi.org/10.1021/acs.orglett.9b01297

Vancouver

Dubovtsev AY, Dar'In DV, Kukushkin VY. Gold(I)-Catalyzed Oxidation of Acyl Acetylenes to Vicinal Tricarbonyls. Organic Letters. 2019 Июнь 7;21(11):4116-4119. https://doi.org/10.1021/acs.orglett.9b01297

Author

Dubovtsev, Alexey Yu ; Dar'In, Dmitry V. ; Kukushkin, Vadim Yu. / Gold(I)-Catalyzed Oxidation of Acyl Acetylenes to Vicinal Tricarbonyls. в: Organic Letters. 2019 ; Том 21, № 11. стр. 4116-4119.

BibTeX

@article{f3482109fad34753afd57a83ab437bfd,
title = "Gold(I)-Catalyzed Oxidation of Acyl Acetylenes to Vicinal Tricarbonyls",
abstract = "Efficient gold(I)-catalyzed oxidation of COR2-functionalized internal alkynes to vicinal tricarbonyl compounds by 2,6-dichloropyridine N-oxide proceeds under mild conditions (DCM, rt). This catalytic reaction provides a good to excellent yielding route to diverse tricarbonyls such as α,β-diketoesters, 1,2,3-triketones, and α,β-diketoamides. The utility of these compounds was also demonstrated by facile one-pot synthesis of important azaheterocyclic systems.",
keywords = "ONE-POT SYNTHESIS, OXO GOLD CARBENES, BIOLOGICAL EVALUATION, CASCADE REACTIONS, BETA-DICARBONYLS, CHEMISTRY, EFFICIENT, ALKYNES, 2,3-DIKETOESTERS, ACCESS",
author = "Dubovtsev, {Alexey Yu} and Dar'In, {Dmitry V.} and Kukushkin, {Vadim Yu}",
year = "2019",
month = jun,
day = "7",
doi = "10.1021/acs.orglett.9b01297",
language = "English",
volume = "21",
pages = "4116--4119",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "11",

}

RIS

TY - JOUR

T1 - Gold(I)-Catalyzed Oxidation of Acyl Acetylenes to Vicinal Tricarbonyls

AU - Dubovtsev, Alexey Yu

AU - Dar'In, Dmitry V.

AU - Kukushkin, Vadim Yu

PY - 2019/6/7

Y1 - 2019/6/7

N2 - Efficient gold(I)-catalyzed oxidation of COR2-functionalized internal alkynes to vicinal tricarbonyl compounds by 2,6-dichloropyridine N-oxide proceeds under mild conditions (DCM, rt). This catalytic reaction provides a good to excellent yielding route to diverse tricarbonyls such as α,β-diketoesters, 1,2,3-triketones, and α,β-diketoamides. The utility of these compounds was also demonstrated by facile one-pot synthesis of important azaheterocyclic systems.

AB - Efficient gold(I)-catalyzed oxidation of COR2-functionalized internal alkynes to vicinal tricarbonyl compounds by 2,6-dichloropyridine N-oxide proceeds under mild conditions (DCM, rt). This catalytic reaction provides a good to excellent yielding route to diverse tricarbonyls such as α,β-diketoesters, 1,2,3-triketones, and α,β-diketoamides. The utility of these compounds was also demonstrated by facile one-pot synthesis of important azaheterocyclic systems.

KW - ONE-POT SYNTHESIS

KW - OXO GOLD CARBENES

KW - BIOLOGICAL EVALUATION

KW - CASCADE REACTIONS

KW - BETA-DICARBONYLS

KW - CHEMISTRY

KW - EFFICIENT

KW - ALKYNES

KW - 2,3-DIKETOESTERS

KW - ACCESS

UR - http://www.scopus.com/inward/record.url?scp=85066904862&partnerID=8YFLogxK

U2 - 10.1021/acs.orglett.9b01297

DO - 10.1021/acs.orglett.9b01297

M3 - Article

C2 - 31090426

AN - SCOPUS:85066904862

VL - 21

SP - 4116

EP - 4119

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 11

ER -

ID: 46034083