Generalization of the Gibbs-Kelvin-Kohler and Ostwald-Freundlich equations for a liquid film on a soluble nanoparticle

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Generalization of the Gibbs-Kelvin-Kohler and Ostwald-Freundlich equations for a liquid film on a soluble nanoparticle. / Shchekin, A. K.; Rusanov, A. I.

в: Journal of Chemical Physics, Том 129, № 15, 154116, 21.10.2008.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{990a56b7257e42b08b91dec1b77dd9a7,

title = "Generalization of the Gibbs-Kelvin-Kohler and Ostwald-Freundlich equations for a liquid film on a soluble nanoparticle",

abstract = "A derivation of chemical equilibrium equations for a spherical thin film of solution around a soluble solid nanoparticle is presented. The equations obtained generalize the Gibbs-Kelvin-Kohler and Ostwald-Freundlich equations for a soluble particle immersed in the bulk phase. The generalized equations describe the dependence of the chemical potentials of a condensate and dissolved nanoparticle matter in the thin solution film, the condensate saturated pressure, and the solubility of the nanoparticle matter on the film thickness, and the nanoparticle size with account of the disjoining pressure of the liquid film. (C) 2008 American Institute of Physics. [DOI: 10.1063/1.2996590]",

keywords = "THERMODYNAMICS, DELIQUESCENCE, CONDENSATION, EQUILIBRIUM, PARTICLES, NUCLEUS, GROWTH",

author = "Shchekin, {A. K.} and Rusanov, {A. I.}",

year = "2008",

month = oct,

day = "21",

doi = "10.1063/1.2996590",

language = "Английский",

volume = "129",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "15",

}

RIS

TY - JOUR

T1 - Generalization of the Gibbs-Kelvin-Kohler and Ostwald-Freundlich equations for a liquid film on a soluble nanoparticle

AU - Shchekin, A. K.

AU - Rusanov, A. I.

PY - 2008/10/21

Y1 - 2008/10/21

N2 - A derivation of chemical equilibrium equations for a spherical thin film of solution around a soluble solid nanoparticle is presented. The equations obtained generalize the Gibbs-Kelvin-Kohler and Ostwald-Freundlich equations for a soluble particle immersed in the bulk phase. The generalized equations describe the dependence of the chemical potentials of a condensate and dissolved nanoparticle matter in the thin solution film, the condensate saturated pressure, and the solubility of the nanoparticle matter on the film thickness, and the nanoparticle size with account of the disjoining pressure of the liquid film. (C) 2008 American Institute of Physics. [DOI: 10.1063/1.2996590]

AB - A derivation of chemical equilibrium equations for a spherical thin film of solution around a soluble solid nanoparticle is presented. The equations obtained generalize the Gibbs-Kelvin-Kohler and Ostwald-Freundlich equations for a soluble particle immersed in the bulk phase. The generalized equations describe the dependence of the chemical potentials of a condensate and dissolved nanoparticle matter in the thin solution film, the condensate saturated pressure, and the solubility of the nanoparticle matter on the film thickness, and the nanoparticle size with account of the disjoining pressure of the liquid film. (C) 2008 American Institute of Physics. [DOI: 10.1063/1.2996590]

KW - THERMODYNAMICS

KW - DELIQUESCENCE

KW - CONDENSATION

KW - EQUILIBRIUM

KW - PARTICLES

KW - NUCLEUS

KW - GROWTH

U2 - 10.1063/1.2996590

DO - 10.1063/1.2996590

M3 - статья

VL - 129

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 15

M1 - 154116

ER -

ID: 75061656