TY - JOUR

T1 - Full-time kinetics of self-assembly and disassembly in micellar solution via the generalized Smoluchowski equation with fusion and fission of surfactant aggregates.

AU - Shchekin, Alexander K.

AU - Babintsev, Ilya A.

AU - Adzhemyan, Loran Ts.

PY - 2016

Y1 - 2016

N2 - Full-time kinetics of self-assembly and disassembly of spherical micelles with their fusion and fission in non-ionic micellar solutions has been considered in detail on the basis of direct numerical solutions of the generalized Smoluchowski equations describing the evolution of the time-dependent concentrations of molecular aggregates for every aggregation number. The cases of instant increase of the monomer concentration up or dilution of a surfactant solution below the critical micelle concentration at large initial deviations from the final equilibrium state have been studied. Different stages in assembly or disassembly of micelles have been described and compared with the results of the stepwise mechanism of monomer attachment-detachment described by the Becker–Döring kinetic equations. A relation of the full-time kinetics to micellar relaxation at small deviations from the equi- librium state has been checked. Published by AIP Publishing. [http://dx.doi.org/10.1063/1.4966233]

AB - Full-time kinetics of self-assembly and disassembly of spherical micelles with their fusion and fission in non-ionic micellar solutions has been considered in detail on the basis of direct numerical solutions of the generalized Smoluchowski equations describing the evolution of the time-dependent concentrations of molecular aggregates for every aggregation number. The cases of instant increase of the monomer concentration up or dilution of a surfactant solution below the critical micelle concentration at large initial deviations from the final equilibrium state have been studied. Different stages in assembly or disassembly of micelles have been described and compared with the results of the stepwise mechanism of monomer attachment-detachment described by the Becker–Döring kinetic equations. A relation of the full-time kinetics to micellar relaxation at small deviations from the equi- librium state has been checked. Published by AIP Publishing. [http://dx.doi.org/10.1063/1.4966233]

KW - micelle aggregation kinetics Smoluchowski equation fusion-fission

U2 - 10.1063/1.4966233

DO - 10.1063/1.4966233

M3 - Article

VL - 145

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

M1 - 174105

ER -