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FTIR Spectroscopy of Intermolecular Interactions of Ethers with Methanol : Cooperativity Effect. / Rakipov, Ilnaz T.; Semenov, Konstantin N.; Petrov, Artem A.; Akhmadiyarov, Aydar A.; Khachatrian, Artashes A.; Klimovitskii, Alexander E.; Solomonov, Boris N.
в: Journal of Solution Chemistry, Том 51, № 10, 10.2022, стр. 1219-1228.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - FTIR Spectroscopy of Intermolecular Interactions of Ethers with Methanol
T2 - Cooperativity Effect
AU - Rakipov, Ilnaz T.
AU - Semenov, Konstantin N.
AU - Petrov, Artem A.
AU - Akhmadiyarov, Aydar A.
AU - Khachatrian, Artashes A.
AU - Klimovitskii, Alexander E.
AU - Solomonov, Boris N.
N1 - Rakipov, I.T., Semenov, K.N., Petrov, A.A. et al. FTIR Spectroscopy of Intermolecular Interactions of Ethers with Methanol: Cooperativity Effect. J Solution Chem 51, 1219–1228 (2022). https://doi.org/10.1007/s10953-022-01193-9
PY - 2022/10
Y1 - 2022/10
N2 - FTIR spectral analysis of solvation effects on the frequencies of O–H stretching vibrations of methanol complexes with linear (diethyl ether, di-n-butyl ether, and diglyme) and cyclic ethers (1,4-dioxane, 12-crown-4, 15-crown-5, and 18-crown-6) was carried out. The comparative analysis of the influence of solvation effects on the frequencies of O–H groups of methanol in aprotic solvents for both free and bound molecules with ethers (B) had been performed. Complexes in proton-donor solvents as well as in chloroform were investigated to quantify the change in the strength of X–H···B (where X = O) hydrogen bonds due to cooperative interactions. The influences of structure and size of the ether cycle on the contribution of the cooperativity effect of methanol with ethers are discussed.
AB - FTIR spectral analysis of solvation effects on the frequencies of O–H stretching vibrations of methanol complexes with linear (diethyl ether, di-n-butyl ether, and diglyme) and cyclic ethers (1,4-dioxane, 12-crown-4, 15-crown-5, and 18-crown-6) was carried out. The comparative analysis of the influence of solvation effects on the frequencies of O–H groups of methanol in aprotic solvents for both free and bound molecules with ethers (B) had been performed. Complexes in proton-donor solvents as well as in chloroform were investigated to quantify the change in the strength of X–H···B (where X = O) hydrogen bonds due to cooperative interactions. The influences of structure and size of the ether cycle on the contribution of the cooperativity effect of methanol with ethers are discussed.
KW - Cooperativity effects
KW - Hydrogen bonding
KW - IR-Spectroscopy
KW - Linear and cyclic ethers
KW - Methanol
KW - Proton acceptors
KW - Proton donors
UR - http://www.scopus.com/inward/record.url?scp=85136458229&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/99c07ace-fe2c-3f51-a5dd-739942a82ebd/
U2 - 10.1007/s10953-022-01193-9
DO - 10.1007/s10953-022-01193-9
M3 - Article
AN - SCOPUS:85136458229
VL - 51
SP - 1219
EP - 1228
JO - Journal of Solution Chemistry
JF - Journal of Solution Chemistry
SN - 0095-9782
IS - 10
ER -
ID: 100131481