Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
The sequences of Fermi resonances νs ≈ 2νb in the IR spectrum of a fluoroform solution (CHF3) in liquefied krypton have been studied. Here, νs is the CH-stretching vibration and νb is the bending vibration. It has been shown that it is necessary to use an extended set of spectroscopic parameters for the correct description of resonant multiplets at a high degree of vibrational excitation. Among other factors, it is necessary to consider the dependence of the anharmonic interaction constant αsbb on the vibrational quantum numbers. The conclusions are generalized for the arbitrary case of the CH-chromophore CHX3.
Язык оригинала | английский |
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Страницы (с-по) | 1130-1137 |
Число страниц | 8 |
Журнал | OPTICS AND SPECTROSCOPY |
Том | 129 |
Номер выпуска | 10 |
Дата раннего онлайн-доступа | 30 дек 2021 |
DOI | |
Состояние | Опубликовано - 2021 |
ID: 91154423