DOI

The sequences of Fermi resonances νs ≈ 2νb in the IR spectrum of a fluoroform solution (CHF3) in liquefied krypton have been studied. Here, νs is the CH-stretching vibration and νb is the bending vibration. It has been shown that it is necessary to use an extended set of spectroscopic parameters for the correct description of resonant multiplets at a high degree of vibrational excitation. Among other factors, it is necessary to consider the dependence of the anharmonic interaction constant αsbb on the vibrational quantum numbers. The conclusions are generalized for the arbitrary case of the CH-chromophore CHX3.

Язык оригиналаанглийский
Страницы (с-по)1130-1137
Число страниц8
ЖурналOPTICS AND SPECTROSCOPY
Том129
Номер выпуска10
Дата раннего онлайн-доступа30 дек 2021
DOI
СостояниеОпубликовано - 2021

    Предметные области Scopus

  • Электроника, оптика и магнитные материалы
  • Атомная и молекулярная физика и оптика

ID: 91154423