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Four-temperature kinetic model for CO2 vibrational relaxation. / Косарева, Алёна Александровна; Кустова, Елена Владимировна; Кунова, Ольга Владимировна; Нагнибеда, Екатерина Алексеевна.
в: Physics of Fluids, Том 33, № 1, 016103, 01.01.2021.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Four-temperature kinetic model for CO2 vibrational relaxation
AU - Косарева, Алёна Александровна
AU - Кустова, Елена Владимировна
AU - Кунова, Ольга Владимировна
AU - Нагнибеда, Екатерина Алексеевна
N1 - Publisher Copyright: © 2021 Author(s).
PY - 2021/1/1
Y1 - 2021/1/1
N2 - A four-temperature kinetic-theory approach for modeling vibrationally non-equilibrium carbon dioxide flows is developed. The model takes into account all kinds of vibrational-translational energy transitions and inter-mode vibrational energy exchange between symmetric, bending, and asymmetric CO2 modes. The key feature of the model is using the averaged state-resolved relaxation rates instead of conventional Landau-Teller expressions. Spatially homogeneous CO2 vibrational relaxation is studied using the state-to-state, new four-temperature and commonly used three-temperature models. Excellent agreement between four-temperature and state-to-state solutions is found, whereas using the three-temperature model with the Landau-Teller production rates leads to significant loss of accuracy. Numerical efficiency of various approaches is discussed as well as the ways for its improvement.
AB - A four-temperature kinetic-theory approach for modeling vibrationally non-equilibrium carbon dioxide flows is developed. The model takes into account all kinds of vibrational-translational energy transitions and inter-mode vibrational energy exchange between symmetric, bending, and asymmetric CO2 modes. The key feature of the model is using the averaged state-resolved relaxation rates instead of conventional Landau-Teller expressions. Spatially homogeneous CO2 vibrational relaxation is studied using the state-to-state, new four-temperature and commonly used three-temperature models. Excellent agreement between four-temperature and state-to-state solutions is found, whereas using the three-temperature model with the Landau-Teller production rates leads to significant loss of accuracy. Numerical efficiency of various approaches is discussed as well as the ways for its improvement.
KW - DISSOCIATION
KW - FLOWS
KW - MOLECULES
KW - SIMULATION
UR - http://www.scopus.com/inward/record.url?scp=85099226575&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/3f122a06-8fb4-3796-9ba0-2ec30313a552/
U2 - 10.1063/5.0035171
DO - 10.1063/5.0035171
M3 - Article
VL - 33
JO - Physics of Fluids A: Fluid Dynamics
JF - Physics of Fluids A: Fluid Dynamics
SN - 1070-6631
IS - 1
M1 - 016103
ER -
ID: 72578901