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Formation of paramagnetic intermediates under the conditions of Brookhart-type catalyst activation and operation. / Petrovskii, S. K.; Saraev, V. V.; Kraikivskii, P. B.; Gurinovich, N. S.; Matveev, D. A.; Bocharova, V. V.

в: Russian Chemical Bulletin, Том 62, № 6, 06.2013, стр. 1323-1326.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Petrovskii, SK, Saraev, VV, Kraikivskii, PB, Gurinovich, NS, Matveev, DA & Bocharova, VV 2013, 'Formation of paramagnetic intermediates under the conditions of Brookhart-type catalyst activation and operation', Russian Chemical Bulletin, Том. 62, № 6, стр. 1323-1326. https://doi.org/10.1007/s11172-013-0186-y

APA

Petrovskii, S. K., Saraev, V. V., Kraikivskii, P. B., Gurinovich, N. S., Matveev, D. A., & Bocharova, V. V. (2013). Formation of paramagnetic intermediates under the conditions of Brookhart-type catalyst activation and operation. Russian Chemical Bulletin, 62(6), 1323-1326. https://doi.org/10.1007/s11172-013-0186-y

Vancouver

Petrovskii SK, Saraev VV, Kraikivskii PB, Gurinovich NS, Matveev DA, Bocharova VV. Formation of paramagnetic intermediates under the conditions of Brookhart-type catalyst activation and operation. Russian Chemical Bulletin. 2013 Июнь;62(6):1323-1326. https://doi.org/10.1007/s11172-013-0186-y

Author

Petrovskii, S. K. ; Saraev, V. V. ; Kraikivskii, P. B. ; Gurinovich, N. S. ; Matveev, D. A. ; Bocharova, V. V. / Formation of paramagnetic intermediates under the conditions of Brookhart-type catalyst activation and operation. в: Russian Chemical Bulletin. 2013 ; Том 62, № 6. стр. 1323-1326.

BibTeX

@article{374ef4a02aa24cde917fddaede42fae2,
title = "Formation of paramagnetic intermediates under the conditions of Brookhart-type catalyst activation and operation",
abstract = "The formation of two types of paramagnetic species in the catalytic system NiBr2(DAB)/ MAO under real catalytic conditions was found. These are NiII are NiI complexes with the diimine ligand and complexes with the radical anion ligand in the coordination sphere. Under catalysis conditions, these forms are in equilibrium with each other, the equilibrium being shifted towards the radical anion form upon substrate addition.",
keywords = "Brookhart-type catalysts, Catalysis, ESR spectroscopy, Radical anions",
author = "Petrovskii, {S. K.} and Saraev, {V. V.} and Kraikivskii, {P. B.} and Gurinovich, {N. S.} and Matveev, {D. A.} and Bocharova, {V. V.}",
year = "2013",
month = jun,
doi = "10.1007/s11172-013-0186-y",
language = "English",
volume = "62",
pages = "1323--1326",
journal = "Russian Chemical Bulletin",
issn = "1066-5285",
publisher = "Springer Nature",
number = "6",

}

RIS

TY - JOUR

T1 - Formation of paramagnetic intermediates under the conditions of Brookhart-type catalyst activation and operation

AU - Petrovskii, S. K.

AU - Saraev, V. V.

AU - Kraikivskii, P. B.

AU - Gurinovich, N. S.

AU - Matveev, D. A.

AU - Bocharova, V. V.

PY - 2013/6

Y1 - 2013/6

N2 - The formation of two types of paramagnetic species in the catalytic system NiBr2(DAB)/ MAO under real catalytic conditions was found. These are NiII are NiI complexes with the diimine ligand and complexes with the radical anion ligand in the coordination sphere. Under catalysis conditions, these forms are in equilibrium with each other, the equilibrium being shifted towards the radical anion form upon substrate addition.

AB - The formation of two types of paramagnetic species in the catalytic system NiBr2(DAB)/ MAO under real catalytic conditions was found. These are NiII are NiI complexes with the diimine ligand and complexes with the radical anion ligand in the coordination sphere. Under catalysis conditions, these forms are in equilibrium with each other, the equilibrium being shifted towards the radical anion form upon substrate addition.

KW - Brookhart-type catalysts

KW - Catalysis

KW - ESR spectroscopy

KW - Radical anions

UR - http://www.scopus.com/inward/record.url?scp=84898825302&partnerID=8YFLogxK

U2 - 10.1007/s11172-013-0186-y

DO - 10.1007/s11172-013-0186-y

M3 - Article

AN - SCOPUS:84898825302

VL - 62

SP - 1323

EP - 1326

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 6

ER -

ID: 51891034