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Formation of Homo- and Heteronuclear Platinum(II) and Palladium(II) Carbene Complexes in the Reactions of Coordinated Isocyanides with Aminothiazaheterocycles. / Михердов, Александр Сергеевич; Орехова, Юлия Александровна; Боярский, Вадим Павлович.

в: Russian Journal of General Chemistry, Том 88, № 10, 01.10.2018, стр. 2119–2124.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Михердов, АС, Орехова, ЮА & Боярский, ВП 2018, 'Formation of Homo- and Heteronuclear Platinum(II) and Palladium(II) Carbene Complexes in the Reactions of Coordinated Isocyanides with Aminothiazaheterocycles', Russian Journal of General Chemistry, Том. 88, № 10, стр. 2119–2124. https://doi.org/10.1134/S1070363218100158

APA

Михердов, А. С., Орехова, Ю. А., & Боярский, В. П. (2018). Formation of Homo- and Heteronuclear Platinum(II) and Palladium(II) Carbene Complexes in the Reactions of Coordinated Isocyanides with Aminothiazaheterocycles. Russian Journal of General Chemistry, 88(10), 2119–2124. https://doi.org/10.1134/S1070363218100158

Vancouver

Михердов АС, Орехова ЮА, Боярский ВП. Formation of Homo- and Heteronuclear Platinum(II) and Palladium(II) Carbene Complexes in the Reactions of Coordinated Isocyanides with Aminothiazaheterocycles. Russian Journal of General Chemistry. 2018 Окт. 1;88(10):2119–2124. https://doi.org/10.1134/S1070363218100158

Author

Михердов, Александр Сергеевич ; Орехова, Юлия Александровна ; Боярский, Вадим Павлович. / Formation of Homo- and Heteronuclear Platinum(II) and Palladium(II) Carbene Complexes in the Reactions of Coordinated Isocyanides with Aminothiazaheterocycles. в: Russian Journal of General Chemistry. 2018 ; Том 88, № 10. стр. 2119–2124.

BibTeX

@article{e7d6345efba94ff583cd83cd4f8c3b66,
title = "Formation of Homo- and Heteronuclear Platinum(II) and Palladium(II) Carbene Complexes in the Reactions of Coordinated Isocyanides with Aminothiazaheterocycles",
abstract = "The reaction of 5-(trifluoromethyl)-1,3,4-thiadiazol-2-amine with cis-dichlorobis(2,6-dimethylphenyl isocyanide)platinum(II) (cis-[PtCl 2(CNXyl) 2], Xyl = 2,6-Me 2C 6H 3) gave platinum(II) monocarbene complex whose deprotonation with an organic base generated a nucleophilic species capable of reacting with palladium(II) and platinum(II) bis(isocyanide) complexes to afford homo- and heteronuclear isocyanide/carbene structures. ",
keywords = "aminothiazaheterocycles, heteronuclear carbene complexes, isocyanide ligands, palladium(II) diaminocarbene complexes, platinum(II) diaminocarbene complexes, SONOGASHIRA, LIGANDS, ACYCLIC DIAMINOCARBENE COMPLEXES, COPPER-FREE, ISONITRILES, EFFICIENT CATALYSTS, GOLD(I)",
author = "Михердов, {Александр Сергеевич} and Орехова, {Юлия Александровна} and Боярский, {Вадим Павлович}",
note = "Funding Information: This study was performed under financial support by the Russian Foundation for Basic Research (project no. 18-03-00119, synthesis and structure of carbene palladium complexes; project no. 18-33-00704mol_a, synthesis and structure of carbene platinum complexes) using the facilities of the Magnetic Resonance Research Center, Chemical Analysis and Materials Research Center, and Chemistry Educational Center of the St. Petersburg State University.",
year = "2018",
month = oct,
day = "1",
doi = "10.1134/S1070363218100158",
language = "English",
volume = "88",
pages = "2119–2124",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "10",

}

RIS

TY - JOUR

T1 - Formation of Homo- and Heteronuclear Platinum(II) and Palladium(II) Carbene Complexes in the Reactions of Coordinated Isocyanides with Aminothiazaheterocycles

AU - Михердов, Александр Сергеевич

AU - Орехова, Юлия Александровна

AU - Боярский, Вадим Павлович

N1 - Funding Information: This study was performed under financial support by the Russian Foundation for Basic Research (project no. 18-03-00119, synthesis and structure of carbene palladium complexes; project no. 18-33-00704mol_a, synthesis and structure of carbene platinum complexes) using the facilities of the Magnetic Resonance Research Center, Chemical Analysis and Materials Research Center, and Chemistry Educational Center of the St. Petersburg State University.

PY - 2018/10/1

Y1 - 2018/10/1

N2 - The reaction of 5-(trifluoromethyl)-1,3,4-thiadiazol-2-amine with cis-dichlorobis(2,6-dimethylphenyl isocyanide)platinum(II) (cis-[PtCl 2(CNXyl) 2], Xyl = 2,6-Me 2C 6H 3) gave platinum(II) monocarbene complex whose deprotonation with an organic base generated a nucleophilic species capable of reacting with palladium(II) and platinum(II) bis(isocyanide) complexes to afford homo- and heteronuclear isocyanide/carbene structures.

AB - The reaction of 5-(trifluoromethyl)-1,3,4-thiadiazol-2-amine with cis-dichlorobis(2,6-dimethylphenyl isocyanide)platinum(II) (cis-[PtCl 2(CNXyl) 2], Xyl = 2,6-Me 2C 6H 3) gave platinum(II) monocarbene complex whose deprotonation with an organic base generated a nucleophilic species capable of reacting with palladium(II) and platinum(II) bis(isocyanide) complexes to afford homo- and heteronuclear isocyanide/carbene structures.

KW - aminothiazaheterocycles

KW - heteronuclear carbene complexes

KW - isocyanide ligands

KW - palladium(II) diaminocarbene complexes

KW - platinum(II) diaminocarbene complexes

KW - SONOGASHIRA

KW - LIGANDS

KW - ACYCLIC DIAMINOCARBENE COMPLEXES

KW - COPPER-FREE

KW - ISONITRILES

KW - EFFICIENT CATALYSTS

KW - GOLD(I)

UR - http://www.scopus.com/inward/record.url?scp=85057788784&partnerID=8YFLogxK

UR - http://link.springer.com/10.1134/S1070363218100158

UR - http://www.mendeley.com/research/formation-homo-heteronuclear-platinumii-palladiumii-carbene-complexes-reactions-coordinated-isocyani

U2 - 10.1134/S1070363218100158

DO - 10.1134/S1070363218100158

M3 - Article

VL - 88

SP - 2119

EP - 2124

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 10

ER -

ID: 35457198