TY - JOUR

T1 - Foam-like Ce–Fe–O-based nanocomposites as catalytic platforms for efficient hydrogen oxidation in air

AU - Cam, T.S.

AU - Omarov, S.

AU - Trofimuk, A.

AU - Lebedev, V.

AU - Panchuk, V.

AU - Semenov, V.

AU - Nguyen, A.T.

AU - Popkov, V.

N1 - Export Date: 28 November 2023 Адрес для корреспонденции: Cam, T.S.; Institute of Fundamental and Applied Sciences (Ho Chi Minh City 700000), Viet Nam; эл. почта: camthanhson@duytan.edu.vn Текст о финансировании 1: The authors are grateful to E.A. Zaboeva for her assistance in carrying out the synthesis of Ce–Fe–O-based nanopowders using the glycine-nitrate combustion method. This research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors. Пристатейные ссылки: Shepelin, V., Koshmanov, D., Chepelin, E., Catalysts for hydrogen removal: kinetic paradox and functioning at high concentration of hydrogen (2009) Int. Conf. Hydrog. 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PY - 2023/9/1

Y1 - 2023/9/1

N2 - Foam-like nanocomposites of the Ce–Fe–O system with two (c-CeO2, am-F2O3), three (c-CeO2, o-CeFeO3, α-F2O3), or four phases (c-CeO2, o-CeFeO3, α-F2O3, am-Fe2O3) were synthesized using the RedOx reaction of glycine-nitrate combustion. The glycine/nitrate ratio (G/N) varied from deficient (0.2, 0.4) and stoichiometric (0.6) to excess ratios of glycine (0.8, 1.0, 1.2, 1.4). PXRD, 57Fe Mössbauer spectroscopy, N2-physisorption, TEM, H2-TPD, O2-TPD, and H2-TPR were used to examine the characteristics of the obtained samples. The average crystallite size of the obtained composites was in the range of 1.3–31.3 nm, 33.4–50.7 nm, and 10.1–33.9 nm for c-CeO2, o-CeFeO3, and α-Fe2O3, respectively. The lowest SBET (1.5 m2/g) belonged to the case of stoichiometric G/N, while the highest value (49.2 m2/g) was found in the case of the highest amount of glycine (G/N = 1.4); the latter case also had the largest total pore volume (Vp = 0.182 cm3/g) when compared to the others. Moreover, the advanced catalytic performance of foamy Ce–Fe–O-based nanocomposites toward H2 combustion in air was found with t10 = 275 °C, t50 = 345 °C, and Ea = 76.9 kJ/mol for sample G/N = 1.2. The higher activity of sample G/N = 1.2 in catalysis was attributed to different properties of the composite, including an appropriate component phase ratio, the smaller size of crystallites, higher specific surface area, higher reducibility,oxygen capacity, etc. The findings make it possible to carry out the directed synthesis of catalysts based on the Ce–Fe–O system with specific phases, dispersion, and morphological composition for efficient hydrogen oxidation at moderate temperatures. © 2023 Vietnam National University, Hanoi

AB - Foam-like nanocomposites of the Ce–Fe–O system with two (c-CeO2, am-F2O3), three (c-CeO2, o-CeFeO3, α-F2O3), or four phases (c-CeO2, o-CeFeO3, α-F2O3, am-Fe2O3) were synthesized using the RedOx reaction of glycine-nitrate combustion. The glycine/nitrate ratio (G/N) varied from deficient (0.2, 0.4) and stoichiometric (0.6) to excess ratios of glycine (0.8, 1.0, 1.2, 1.4). PXRD, 57Fe Mössbauer spectroscopy, N2-physisorption, TEM, H2-TPD, O2-TPD, and H2-TPR were used to examine the characteristics of the obtained samples. The average crystallite size of the obtained composites was in the range of 1.3–31.3 nm, 33.4–50.7 nm, and 10.1–33.9 nm for c-CeO2, o-CeFeO3, and α-Fe2O3, respectively. The lowest SBET (1.5 m2/g) belonged to the case of stoichiometric G/N, while the highest value (49.2 m2/g) was found in the case of the highest amount of glycine (G/N = 1.4); the latter case also had the largest total pore volume (Vp = 0.182 cm3/g) when compared to the others. Moreover, the advanced catalytic performance of foamy Ce–Fe–O-based nanocomposites toward H2 combustion in air was found with t10 = 275 °C, t50 = 345 °C, and Ea = 76.9 kJ/mol for sample G/N = 1.2. The higher activity of sample G/N = 1.2 in catalysis was attributed to different properties of the composite, including an appropriate component phase ratio, the smaller size of crystallites, higher specific surface area, higher reducibility,oxygen capacity, etc. The findings make it possible to carry out the directed synthesis of catalysts based on the Ce–Fe–O system with specific phases, dispersion, and morphological composition for efficient hydrogen oxidation at moderate temperatures. © 2023 Vietnam National University, Hanoi

KW - CeO2–Fe2O3

KW - Cerium orthoferrite

KW - Glycine-nitrate condition

KW - Hydrogen catalytic oxidation

KW - Perovskite

KW - Solution combustion synthesis

UR - https://www.mendeley.com/catalogue/4d2dd481-eda7-3e06-9c23-a527f4265544/

U2 - 10.1016/j.jsamd.2023.100596

DO - 10.1016/j.jsamd.2023.100596

M3 - статья

VL - 8

JO - Journal of Science-Advanced Materials and Devices

JF - Journal of Science-Advanced Materials and Devices

SN - 2468-2284

IS - 3

M1 - 100596

ER -