Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Fluorinated mercaptobenzothiazolates of lanthanides : Synthesis, structure and photoluminescence. / Ilichev, Vasily A.; Blinova, Lubov I.; Rozhkov, Anton V.; Balashova, Tatyana V.; Rumyantcev, Roman V.; Fukin, Georgy K.; Bochkarev, Mikhail N.
в: Journal of Molecular Structure, Том 1148, 15.11.2017, стр. 201-205.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Fluorinated mercaptobenzothiazolates of lanthanides
T2 - Synthesis, structure and photoluminescence
AU - Ilichev, Vasily A.
AU - Blinova, Lubov I.
AU - Rozhkov, Anton V.
AU - Balashova, Tatyana V.
AU - Rumyantcev, Roman V.
AU - Fukin, Georgy K.
AU - Bochkarev, Mikhail N.
PY - 2017/11/15
Y1 - 2017/11/15
N2 - In search of new fully fluorinated ligands which effectively sensitized the lanthanide luminescence the 4,5,6,7-tetrafluoro-1,3-benzothiazol-2(3Н)-thione (HmbtF) was proposed. Based on this ligand a set of new complexes LnL3(THF)2 (Ln1) (Ln = Nd, Gd, Tb, Dy, Er, Yb) was synthesized and their luminescence were studied. The structure of the compounds was established with an example of Gd derivative. The triplet state energy of mbtF was found to be 21500 cm−1 that enables the resonant energy transfer to Dy3+, Tb3+, Nd3+ and Er3+ ions and stipulates metal-centered emission of some complexes. In case of Yb1 the observed luminescence of Yb3+ ion probably occurs due to the non-resonant energy transfer.
AB - In search of new fully fluorinated ligands which effectively sensitized the lanthanide luminescence the 4,5,6,7-tetrafluoro-1,3-benzothiazol-2(3Н)-thione (HmbtF) was proposed. Based on this ligand a set of new complexes LnL3(THF)2 (Ln1) (Ln = Nd, Gd, Tb, Dy, Er, Yb) was synthesized and their luminescence were studied. The structure of the compounds was established with an example of Gd derivative. The triplet state energy of mbtF was found to be 21500 cm−1 that enables the resonant energy transfer to Dy3+, Tb3+, Nd3+ and Er3+ ions and stipulates metal-centered emission of some complexes. In case of Yb1 the observed luminescence of Yb3+ ion probably occurs due to the non-resonant energy transfer.
KW - Energy transfer
KW - Fully fluorinated ligand
KW - Lanthanides
KW - Photoluminescence
UR - http://www.scopus.com/inward/record.url?scp=85024877272&partnerID=8YFLogxK
U2 - 10.1016/j.molstruc.2017.07.035
DO - 10.1016/j.molstruc.2017.07.035
M3 - Article
AN - SCOPUS:85024877272
VL - 1148
SP - 201
EP - 205
JO - Journal of Molecular Structure
JF - Journal of Molecular Structure
SN - 0022-2860
ER -
ID: 39928010