Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
First discovery and formation process of authigenic siderite from gas hydrate-bearing mud volcanoes in fresh water : Lake Baikal, eastern Siberia. / Krylov, Alexey; Khlystov, Oleg; Zemskaya, Tamara; Minami, Hirotsugu; Hachikubo, Akihiro; Nunokawa, Yutaka; Kida, Masato; Shoji, Hitoshi; Naudts, Lieven; Poort, Jeffrey; Pogodaeva, Tatiana.
в: Geophysical Research Letters, Том 35, № 5, L05405, 16.03.2008.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - First discovery and formation process of authigenic siderite from gas hydrate-bearing mud volcanoes in fresh water
T2 - Lake Baikal, eastern Siberia
AU - Krylov, Alexey
AU - Khlystov, Oleg
AU - Zemskaya, Tamara
AU - Minami, Hirotsugu
AU - Hachikubo, Akihiro
AU - Nunokawa, Yutaka
AU - Kida, Masato
AU - Shoji, Hitoshi
AU - Naudts, Lieven
AU - Poort, Jeffrey
AU - Pogodaeva, Tatiana
PY - 2008/3/16
Y1 - 2008/3/16
N2 - We report on the first authigenic siderite (FeCO3) concretions recovered from near-bottom sediments at gas hydrate-bearing mud volcanoes in fresh water (Lake Baikal, Eastern Siberia). The carbonates appear as firm 'plate-type' formations at the Malenky mud volcano (Southern Baikal Basin) and as soft nodules at the K-2 mud volcano (Central Baikal Basin). Calcium is the main divalent component which substitutes iron in the carbonate lattice (7 to 20 mol%). The δ 13C values of the carbonates (+3.3 to +6.8‰ at Malenky, and +16.5 to +21.9‰ PDB at K-2) indicate that their formation is due to methanogenesis. The latter was most likely caused by the microbial methyl-type (acetate) fermentation that is suggested from the isotopic composition of the accompanying methane hydrates and dissolved methane. General depletion of the siderites in 18O (-11.6 to -9.9‰ at Malenky, and -13.9 to -12.3‰ PDB at K-2) is mainly inherited from the isotope composition of pore water (-15.2 to -15.4‰ SMOW) at ambient temperature (3.5°C).
AB - We report on the first authigenic siderite (FeCO3) concretions recovered from near-bottom sediments at gas hydrate-bearing mud volcanoes in fresh water (Lake Baikal, Eastern Siberia). The carbonates appear as firm 'plate-type' formations at the Malenky mud volcano (Southern Baikal Basin) and as soft nodules at the K-2 mud volcano (Central Baikal Basin). Calcium is the main divalent component which substitutes iron in the carbonate lattice (7 to 20 mol%). The δ 13C values of the carbonates (+3.3 to +6.8‰ at Malenky, and +16.5 to +21.9‰ PDB at K-2) indicate that their formation is due to methanogenesis. The latter was most likely caused by the microbial methyl-type (acetate) fermentation that is suggested from the isotopic composition of the accompanying methane hydrates and dissolved methane. General depletion of the siderites in 18O (-11.6 to -9.9‰ at Malenky, and -13.9 to -12.3‰ PDB at K-2) is mainly inherited from the isotope composition of pore water (-15.2 to -15.4‰ SMOW) at ambient temperature (3.5°C).
UR - http://www.scopus.com/inward/record.url?scp=43549110302&partnerID=8YFLogxK
U2 - 10.1029/2007GL032917
DO - 10.1029/2007GL032917
M3 - Article
AN - SCOPUS:43549110302
VL - 35
JO - Geophysical Research Letters
JF - Geophysical Research Letters
SN - 0094-8276
IS - 5
M1 - L05405
ER -
ID: 47750554