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Features of the Formation of the [(O)VIV(C2O4)(Phen)(H2O)] Complex in the Malic Acid Oxidation Process. / Panina, N. S.; Nikandrov, E. M.; Laptenkova, A. V.; Selyutin, A. A.; Ruzanov, D. O.; Belyaev, A. N.

в: Russian Journal of General Chemistry, Том 89, № 4, 01.04.2019, стр. 741-746.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Panina, NS, Nikandrov, EM, Laptenkova, AV, Selyutin, AA, Ruzanov, DO & Belyaev, AN 2019, 'Features of the Formation of the [(O)VIV(C2O4)(Phen)(H2O)] Complex in the Malic Acid Oxidation Process', Russian Journal of General Chemistry, Том. 89, № 4, стр. 741-746. https://doi.org/10.1134/S1070363219040170

APA

Panina, N. S., Nikandrov, E. M., Laptenkova, A. V., Selyutin, A. A., Ruzanov, D. O., & Belyaev, A. N. (2019). Features of the Formation of the [(O)VIV(C2O4)(Phen)(H2O)] Complex in the Malic Acid Oxidation Process. Russian Journal of General Chemistry, 89(4), 741-746. https://doi.org/10.1134/S1070363219040170

Vancouver

Panina NS, Nikandrov EM, Laptenkova AV, Selyutin AA, Ruzanov DO, Belyaev AN. Features of the Formation of the [(O)VIV(C2O4)(Phen)(H2O)] Complex in the Malic Acid Oxidation Process. Russian Journal of General Chemistry. 2019 Апр. 1;89(4):741-746. https://doi.org/10.1134/S1070363219040170

Author

Panina, N. S. ; Nikandrov, E. M. ; Laptenkova, A. V. ; Selyutin, A. A. ; Ruzanov, D. O. ; Belyaev, A. N. / Features of the Formation of the [(O)VIV(C2O4)(Phen)(H2O)] Complex in the Malic Acid Oxidation Process. в: Russian Journal of General Chemistry. 2019 ; Том 89, № 4. стр. 741-746.

BibTeX

@article{6a901b6455b74a55aaf5934a9d8058da,
title = "Features of the Formation of the [(O)VIV(C2O4)(Phen)(H2O)] Complex in the Malic Acid Oxidation Process",
abstract = "Complex [(O)VIV(C2O4)(Phen)(H2O)] was obtained on the basis of V2O5 and malic acid in the presence of concentrated HNO3 and phenanthroline. Its structure was determined by the X-ray structural analysis; its magnetic susceptibility was measured. The role of the VO2+ and VO2+ cations in the oxidation and complex-formation processes was considered. A method for the conversion of malic acid to oxalate anions through the formation of oxaloacetic acid and the intermediate products of its decarboxylation reactions was proposed. It was shown by the DFT M06/6-31G(d,p) method that the transition state energy decreases in the way of the HOC(O)C(0)CH2-COOH bond breakage during decarboxylation compared with the free acid in the intermediate of its anion with VO2+.",
keywords = "carboxylic acids, decarboxylation, DFT modeling, vanadium",
author = "Panina, {N. S.} and Nikandrov, {E. M.} and Laptenkova, {A. V.} and Selyutin, {A. A.} and Ruzanov, {D. O.} and Belyaev, {A. N.}",
year = "2019",
month = apr,
day = "1",
doi = "10.1134/S1070363219040170",
language = "English",
volume = "89",
pages = "741--746",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "4",

}

RIS

TY - JOUR

T1 - Features of the Formation of the [(O)VIV(C2O4)(Phen)(H2O)] Complex in the Malic Acid Oxidation Process

AU - Panina, N. S.

AU - Nikandrov, E. M.

AU - Laptenkova, A. V.

AU - Selyutin, A. A.

AU - Ruzanov, D. O.

AU - Belyaev, A. N.

PY - 2019/4/1

Y1 - 2019/4/1

N2 - Complex [(O)VIV(C2O4)(Phen)(H2O)] was obtained on the basis of V2O5 and malic acid in the presence of concentrated HNO3 and phenanthroline. Its structure was determined by the X-ray structural analysis; its magnetic susceptibility was measured. The role of the VO2+ and VO2+ cations in the oxidation and complex-formation processes was considered. A method for the conversion of malic acid to oxalate anions through the formation of oxaloacetic acid and the intermediate products of its decarboxylation reactions was proposed. It was shown by the DFT M06/6-31G(d,p) method that the transition state energy decreases in the way of the HOC(O)C(0)CH2-COOH bond breakage during decarboxylation compared with the free acid in the intermediate of its anion with VO2+.

AB - Complex [(O)VIV(C2O4)(Phen)(H2O)] was obtained on the basis of V2O5 and malic acid in the presence of concentrated HNO3 and phenanthroline. Its structure was determined by the X-ray structural analysis; its magnetic susceptibility was measured. The role of the VO2+ and VO2+ cations in the oxidation and complex-formation processes was considered. A method for the conversion of malic acid to oxalate anions through the formation of oxaloacetic acid and the intermediate products of its decarboxylation reactions was proposed. It was shown by the DFT M06/6-31G(d,p) method that the transition state energy decreases in the way of the HOC(O)C(0)CH2-COOH bond breakage during decarboxylation compared with the free acid in the intermediate of its anion with VO2+.

KW - carboxylic acids

KW - decarboxylation

KW - DFT modeling

KW - vanadium

UR - http://www.scopus.com/inward/record.url?scp=85066258329&partnerID=8YFLogxK

U2 - 10.1134/S1070363219040170

DO - 10.1134/S1070363219040170

M3 - Article

AN - SCOPUS:85066258329

VL - 89

SP - 741

EP - 746

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 4

ER -

ID: 43108579