Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Fe3+ partitioning systematics between orthopyroxene and garnet in mantle peridotite xenoliths and implications for thermobarometry of oxidized and reduced mantle rocks. / Nimis, Paolo; Goncharov, Alexey; Ionov, Dmitri A.; McCammon, Catherine.
в: Contributions of Mineralogy and Petrology, Том 169, № 1, 2015.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Fe3+ partitioning systematics between orthopyroxene and garnet in mantle peridotite xenoliths and implications for thermobarometry of oxidized and reduced mantle rocks
AU - Nimis, Paolo
AU - Goncharov, Alexey
AU - Ionov, Dmitri A.
AU - McCammon, Catherine
PY - 2015
Y1 - 2015
N2 - © 2015, Springer-Verlag Berlin Heidelberg.We have investigated the partitioning of Fe3+ between orthopyroxene (Opx) and garnet (Grt) in well-equilibrated mantle xenoliths using Mössbauer spectroscopy. The samples cover a wide range of P–T conditions (2.1–6.6 GPa, 690–1,412 °C) and geothermal gradients, and are thus representative for Earth’s upper mantle in both on-craton and off-craton continental settings. Garnet has Fe3+/Fetot ratios of 0.03–0.13 and Fe2O3 contents of 0.24–1.00 wt%. Orthopyroxene has, on average, lower Fe3+/Fetot ratios (0.01–0.09) and Fe2O3 contents (0.05–0.63 wt%). In low-pressure, high-temperature samples, however, Opx is systematically richer in Fe2O3 than the coexisting Grt. The Fe3+ Opx/Grt partition coefficient $$\left({D_{{{\text{Fe}}^{3+}}}^{\text{Opx/Grt}}}\right)$$DFe3+Opx/Grt shows no obvious relationship with temperature, but increases with decreasing pressure and with increasing NaOpx. The observed Opx/Grt Fe3+ systematics imply that the Opx–Grt Fe–Mg exchange thermometer is
AB - © 2015, Springer-Verlag Berlin Heidelberg.We have investigated the partitioning of Fe3+ between orthopyroxene (Opx) and garnet (Grt) in well-equilibrated mantle xenoliths using Mössbauer spectroscopy. The samples cover a wide range of P–T conditions (2.1–6.6 GPa, 690–1,412 °C) and geothermal gradients, and are thus representative for Earth’s upper mantle in both on-craton and off-craton continental settings. Garnet has Fe3+/Fetot ratios of 0.03–0.13 and Fe2O3 contents of 0.24–1.00 wt%. Orthopyroxene has, on average, lower Fe3+/Fetot ratios (0.01–0.09) and Fe2O3 contents (0.05–0.63 wt%). In low-pressure, high-temperature samples, however, Opx is systematically richer in Fe2O3 than the coexisting Grt. The Fe3+ Opx/Grt partition coefficient $$\left({D_{{{\text{Fe}}^{3+}}}^{\text{Opx/Grt}}}\right)$$DFe3+Opx/Grt shows no obvious relationship with temperature, but increases with decreasing pressure and with increasing NaOpx. The observed Opx/Grt Fe3+ systematics imply that the Opx–Grt Fe–Mg exchange thermometer is
U2 - 10.1007/s00410-014-1101-8
DO - 10.1007/s00410-014-1101-8
M3 - Article
VL - 169
JO - Contributions to Mineralogy and Petrology
JF - Contributions to Mineralogy and Petrology
SN - 0010-7999
IS - 1
ER -
ID: 3926885