Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Extractive properties of synergistic mixture of hydrogen dicarbollylcobaltate and N, N, Ń, Ń - Tetraisobutyl - 2, 6 - Dipicolinamide in the water - Nitrobenzene system with regard to Eu3+ and Am3+. / Makrlík, Emanuel; Vanura, Petr; Selucký, Pavel; Babain, Vasily A.; Smirnov, Igor V.
в: Acta Chimica Slovenica, Том 56, № 3, 30.09.2009, стр. 718-722.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Extractive properties of synergistic mixture of hydrogen dicarbollylcobaltate and N, N, Ń, Ń - Tetraisobutyl - 2, 6 - Dipicolinamide in the water - Nitrobenzene system with regard to Eu3+ and Am3+
AU - Makrlík, Emanuel
AU - Vanura, Petr
AU - Selucký, Pavel
AU - Babain, Vasily A.
AU - Smirnov, Igor V.
PY - 2009/9/30
Y1 - 2009/9/30
N2 - Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of N, N, Ń, Ń - tetraisobutyl - 2, 6 - dipicolinamide [T(iBu)DPA, L] has been investigated. The equilibrium data have been explained assuming that the cations HL+, HL+ 2, ML 3 2 + and ML3 3 + (M3+ = Eu3+, Am3+) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined.
AB - Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of N, N, Ń, Ń - tetraisobutyl - 2, 6 - dipicolinamide [T(iBu)DPA, L] has been investigated. The equilibrium data have been explained assuming that the cations HL+, HL+ 2, ML 3 2 + and ML3 3 + (M3+ = Eu3+, Am3+) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined.
KW - 6 - dipicolinamide
KW - Americium
KW - Europium
KW - Extraction and stability constants
KW - Hydrogen dicarbollylcobaltate
KW - N
KW - Ń
KW - Ń - tetraisobutyl - 2
KW - Water-nitrobenzene system
UR - http://www.scopus.com/inward/record.url?scp=70349432388&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:70349432388
VL - 56
SP - 718
EP - 722
JO - Acta Chimica Slovenica
JF - Acta Chimica Slovenica
SN - 1318-0207
IS - 3
ER -
ID: 42868027