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Extractive properties of synergistic mixture of hydrogen dicarbollylcobaltate and N, N, Ń, Ń - Tetraisobutyl - 2, 6 - Dipicolinamide in the water - Nitrobenzene system with regard to Eu3+ and Am3+. / Makrlík, Emanuel; Vanura, Petr; Selucký, Pavel; Babain, Vasily A.; Smirnov, Igor V.

в: Acta Chimica Slovenica, Том 56, № 3, 30.09.2009, стр. 718-722.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{7a53ed4d98e14e0e987075490b99277f,
title = "Extractive properties of synergistic mixture of hydrogen dicarbollylcobaltate and N, N, {\'N}, {\'N} - Tetraisobutyl - 2, 6 - Dipicolinamide in the water - Nitrobenzene system with regard to Eu3+ and Am3+",
abstract = "Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of N, N, {\'N}, {\'N} - tetraisobutyl - 2, 6 - dipicolinamide [T(iBu)DPA, L] has been investigated. The equilibrium data have been explained assuming that the cations HL+, HL+ 2, ML 3 2 + and ML3 3 + (M3+ = Eu3+, Am3+) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined.",
keywords = "6 - dipicolinamide, Americium, Europium, Extraction and stability constants, Hydrogen dicarbollylcobaltate, N, {\'N}, {\'N} - tetraisobutyl - 2, Water-nitrobenzene system",
author = "Emanuel Makrl{\'i}k and Petr Vanura and Pavel Seluck{\'y} and Babain, {Vasily A.} and Smirnov, {Igor V.}",
year = "2009",
month = sep,
day = "30",
language = "English",
volume = "56",
pages = "718--722",
journal = "Acta Chimica Slovenica",
issn = "1318-0207",
publisher = "Slovensko Kemijsko Drustvo",
number = "3",

}

RIS

TY - JOUR

T1 - Extractive properties of synergistic mixture of hydrogen dicarbollylcobaltate and N, N, Ń, Ń - Tetraisobutyl - 2, 6 - Dipicolinamide in the water - Nitrobenzene system with regard to Eu3+ and Am3+

AU - Makrlík, Emanuel

AU - Vanura, Petr

AU - Selucký, Pavel

AU - Babain, Vasily A.

AU - Smirnov, Igor V.

PY - 2009/9/30

Y1 - 2009/9/30

N2 - Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of N, N, Ń, Ń - tetraisobutyl - 2, 6 - dipicolinamide [T(iBu)DPA, L] has been investigated. The equilibrium data have been explained assuming that the cations HL+, HL+ 2, ML 3 2 + and ML3 3 + (M3+ = Eu3+, Am3+) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined.

AB - Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of N, N, Ń, Ń - tetraisobutyl - 2, 6 - dipicolinamide [T(iBu)DPA, L] has been investigated. The equilibrium data have been explained assuming that the cations HL+, HL+ 2, ML 3 2 + and ML3 3 + (M3+ = Eu3+, Am3+) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined.

KW - 6 - dipicolinamide

KW - Americium

KW - Europium

KW - Extraction and stability constants

KW - Hydrogen dicarbollylcobaltate

KW - N

KW - Ń

KW - Ń - tetraisobutyl - 2

KW - Water-nitrobenzene system

UR - http://www.scopus.com/inward/record.url?scp=70349432388&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:70349432388

VL - 56

SP - 718

EP - 722

JO - Acta Chimica Slovenica

JF - Acta Chimica Slovenica

SN - 1318-0207

IS - 3

ER -

ID: 42868027