Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Extraction of americium and europium by phosphorylated calix-arenes. / Smireov, I.; Babain, V.; Efremova, T.; Kalchenko, V.
в: Journal of Nuclear Science and Technology, Том 39, 01.01.2002, стр. 321-324.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Extraction of americium and europium by phosphorylated calix-arenes
AU - Smireov, I.
AU - Babain, V.
AU - Efremova, T.
AU - Kalchenko, V.
PY - 2002/1/1
Y1 - 2002/1/1
N2 - Extraction of Am and Eu from HNO3 media by phosphorylated calix-arenes in m-nitrobenzotrifluoride was studied and the following was established:• organophosphorus substituents affect the extraction properties of calix-arenes in the same manner as in the case of routine organophosphorus compounds; • calix[4]phosphine oxides and calix[4]phosphinic acid demonstrate considerable cooperative effect and extract Am and Eu about 100-times more efficient than corresponding monophosphoryl compounds; • calix[4]tetraphosphine oxides form disolvates with Am and Eu; • transfer from phosphorylated calix[4] to calix[6]arenes, i.e. increase in number of donor P=O groups, has practically no influence on extraction of Am and Eu; • only calix[4]carbamoyl extracts Am better than Eu; • as to extraction ability, calix[4]dioxide and calix[4]carbamoyl are close to conventional diphosphine dioxides and carbamoylphosphine oxides. © 2002 Atomic Energy Society of Japan.
AB - Extraction of Am and Eu from HNO3 media by phosphorylated calix-arenes in m-nitrobenzotrifluoride was studied and the following was established:• organophosphorus substituents affect the extraction properties of calix-arenes in the same manner as in the case of routine organophosphorus compounds; • calix[4]phosphine oxides and calix[4]phosphinic acid demonstrate considerable cooperative effect and extract Am and Eu about 100-times more efficient than corresponding monophosphoryl compounds; • calix[4]tetraphosphine oxides form disolvates with Am and Eu; • transfer from phosphorylated calix[4] to calix[6]arenes, i.e. increase in number of donor P=O groups, has practically no influence on extraction of Am and Eu; • only calix[4]carbamoyl extracts Am better than Eu; • as to extraction ability, calix[4]dioxide and calix[4]carbamoyl are close to conventional diphosphine dioxides and carbamoylphosphine oxides. © 2002 Atomic Energy Society of Japan.
KW - Americium
KW - Europium
KW - Extraction
KW - Phosphorylated calix-arenes
UR - http://www.scopus.com/inward/record.url?scp=85010608427&partnerID=8YFLogxK
U2 - 10.1080/00223131.2002.10875473
DO - 10.1080/00223131.2002.10875473
M3 - Article
AN - SCOPUS:85010608427
VL - 39
SP - 321
EP - 324
JO - Journal of Nuclear Science and Technology
JF - Journal of Nuclear Science and Technology
SN - 0022-3131
ER -
ID: 114019058