Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure. / Golikova, Alexandra; Shasherina, Anna; Anufrikov, Yuri; Misikov, Georgii; Toikka, Maria; Zvereva, Irina; Toikka, Alexander.
в: International Journal of Molecular Sciences, Том 24, № 6, 5137, 07.03.2023.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure
AU - Golikova, Alexandra
AU - Shasherina, Anna
AU - Anufrikov, Yuri
AU - Misikov, Georgii
AU - Toikka, Maria
AU - Zvereva, Irina
AU - Toikka, Alexander
PY - 2023/3/7
Y1 - 2023/3/7
N2 - The data on molar excess enthalpies, HmE, for the binary mixtures acetic acid + n-butanol, acetic acid + n-butyl acetate and n-butanol + n-butyl acetate at 313.15 K and atmospheric pressure were obtained with use of the C80 isothermal mixing calorimeter (Setaram). The correlation of the data was carried out using the NRTL model and Redlich-Kister equation. A comparative analysis with the literature data on all available binary subsystems of the quaternary system was carried out. Other thermodynamic properties (Cp,mE, SmE, ΔmixSm, GmE and ΔmixGm) of the binary systems were estimated using literature data and well-known formulas of classical thermodynamics.
AB - The data on molar excess enthalpies, HmE, for the binary mixtures acetic acid + n-butanol, acetic acid + n-butyl acetate and n-butanol + n-butyl acetate at 313.15 K and atmospheric pressure were obtained with use of the C80 isothermal mixing calorimeter (Setaram). The correlation of the data was carried out using the NRTL model and Redlich-Kister equation. A comparative analysis with the literature data on all available binary subsystems of the quaternary system was carried out. Other thermodynamic properties (Cp,mE, SmE, ΔmixSm, GmE and ΔmixGm) of the binary systems were estimated using literature data and well-known formulas of classical thermodynamics.
KW - heat of mixing
KW - calorimetry
KW - n-butyl acetate
KW - thermochemistry
KW - Redlich–Kister equation
KW - NRTL
KW - Butanols
KW - 1-Butanol
KW - Acetic Acid
KW - Water
KW - Thermodynamics
KW - Atmospheric Pressure
UR - https://www.mendeley.com/catalogue/c6893278-10a7-30ca-b75e-3db8aab9c731/
U2 - 10.3390/ijms24065137
DO - 10.3390/ijms24065137
M3 - Article
C2 - 36982213
VL - 24
JO - International Journal of Molecular Sciences
JF - International Journal of Molecular Sciences
SN - 1422-0067
IS - 6
M1 - 5137
ER -
ID: 104473825