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Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure. / Golikova, Alexandra; Shasherina, Anna; Anufrikov, Yuri; Misikov, Georgii; Toikka, Maria; Zvereva, Irina; Toikka, Alexander.

в: International Journal of Molecular Sciences, Том 24, № 6, 5137, 07.03.2023.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{b8466debc9bf4bdead918d08d8f342d9,
title = "Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure",
abstract = "The data on molar excess enthalpies, HmE, for the binary mixtures acetic acid + n-butanol, acetic acid + n-butyl acetate and n-butanol + n-butyl acetate at 313.15 K and atmospheric pressure were obtained with use of the C80 isothermal mixing calorimeter (Setaram). The correlation of the data was carried out using the NRTL model and Redlich-Kister equation. A comparative analysis with the literature data on all available binary subsystems of the quaternary system was carried out. Other thermodynamic properties (Cp,mE, SmE, ΔmixSm, GmE and ΔmixGm) of the binary systems were estimated using literature data and well-known formulas of classical thermodynamics.",
keywords = "heat of mixing, calorimetry, n-butyl acetate, thermochemistry, Redlich–Kister equation, NRTL, Butanols, 1-Butanol, Acetic Acid, Water, Thermodynamics, Atmospheric Pressure",
author = "Alexandra Golikova and Anna Shasherina and Yuri Anufrikov and Georgii Misikov and Maria Toikka and Irina Zvereva and Alexander Toikka",
year = "2023",
month = mar,
day = "7",
doi = "10.3390/ijms24065137",
language = "English",
volume = "24",
journal = "International Journal of Molecular Sciences",
issn = "1422-0067",
publisher = "MDPI AG",
number = "6",

}

RIS

TY - JOUR

T1 - Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure

AU - Golikova, Alexandra

AU - Shasherina, Anna

AU - Anufrikov, Yuri

AU - Misikov, Georgii

AU - Toikka, Maria

AU - Zvereva, Irina

AU - Toikka, Alexander

PY - 2023/3/7

Y1 - 2023/3/7

N2 - The data on molar excess enthalpies, HmE, for the binary mixtures acetic acid + n-butanol, acetic acid + n-butyl acetate and n-butanol + n-butyl acetate at 313.15 K and atmospheric pressure were obtained with use of the C80 isothermal mixing calorimeter (Setaram). The correlation of the data was carried out using the NRTL model and Redlich-Kister equation. A comparative analysis with the literature data on all available binary subsystems of the quaternary system was carried out. Other thermodynamic properties (Cp,mE, SmE, ΔmixSm, GmE and ΔmixGm) of the binary systems were estimated using literature data and well-known formulas of classical thermodynamics.

AB - The data on molar excess enthalpies, HmE, for the binary mixtures acetic acid + n-butanol, acetic acid + n-butyl acetate and n-butanol + n-butyl acetate at 313.15 K and atmospheric pressure were obtained with use of the C80 isothermal mixing calorimeter (Setaram). The correlation of the data was carried out using the NRTL model and Redlich-Kister equation. A comparative analysis with the literature data on all available binary subsystems of the quaternary system was carried out. Other thermodynamic properties (Cp,mE, SmE, ΔmixSm, GmE and ΔmixGm) of the binary systems were estimated using literature data and well-known formulas of classical thermodynamics.

KW - heat of mixing

KW - calorimetry

KW - n-butyl acetate

KW - thermochemistry

KW - Redlich–Kister equation

KW - NRTL

KW - Butanols

KW - 1-Butanol

KW - Acetic Acid

KW - Water

KW - Thermodynamics

KW - Atmospheric Pressure

UR - https://www.mendeley.com/catalogue/c6893278-10a7-30ca-b75e-3db8aab9c731/

U2 - 10.3390/ijms24065137

DO - 10.3390/ijms24065137

M3 - Article

C2 - 36982213

VL - 24

JO - International Journal of Molecular Sciences

JF - International Journal of Molecular Sciences

SN - 1422-0067

IS - 6

M1 - 5137

ER -

ID: 104473825