Standard

Excess enthalpies and heat of esterification reaction in ethanol plus acetic acid plus ethyl acetate plus water system at 313.15 K. / Golikova, Alexandra; Tsvetov, Nikita; Samarov, Artemiy; Toikka, Maria; Zvereva, Irina; Trofimova, Maya; Toikka, Alexander.

в: Journal of Thermal Analysis and Calorimetry, Том 139, № 2, 01.2020, стр. 1301-1307.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Golikova, A, Tsvetov, N, Samarov, A, Toikka, M, Zvereva, I, Trofimova, M & Toikka, A 2020, 'Excess enthalpies and heat of esterification reaction in ethanol plus acetic acid plus ethyl acetate plus water system at 313.15 K', Journal of Thermal Analysis and Calorimetry, Том. 139, № 2, стр. 1301-1307. https://doi.org/10.1007/s10973-019-08488-y

APA

Golikova, A., Tsvetov, N., Samarov, A., Toikka, M., Zvereva, I., Trofimova, M., & Toikka, A. (2020). Excess enthalpies and heat of esterification reaction in ethanol plus acetic acid plus ethyl acetate plus water system at 313.15 K. Journal of Thermal Analysis and Calorimetry, 139(2), 1301-1307. https://doi.org/10.1007/s10973-019-08488-y

Vancouver

Golikova A, Tsvetov N, Samarov A, Toikka M, Zvereva I, Trofimova M и пр. Excess enthalpies and heat of esterification reaction in ethanol plus acetic acid plus ethyl acetate plus water system at 313.15 K. Journal of Thermal Analysis and Calorimetry. 2020 Янв.;139(2):1301-1307. https://doi.org/10.1007/s10973-019-08488-y

Author

Golikova, Alexandra ; Tsvetov, Nikita ; Samarov, Artemiy ; Toikka, Maria ; Zvereva, Irina ; Trofimova, Maya ; Toikka, Alexander. / Excess enthalpies and heat of esterification reaction in ethanol plus acetic acid plus ethyl acetate plus water system at 313.15 K. в: Journal of Thermal Analysis and Calorimetry. 2020 ; Том 139, № 2. стр. 1301-1307.

BibTeX

@article{98c44d848ab243a08f3c939f10384de4,
title = "Excess enthalpies and heat of esterification reaction in ethanol plus acetic acid plus ethyl acetate plus water system at 313.15 K",
abstract = "The excess enthalpies for ethanol + acetic acid + ethyl acetate + water system in the chemically equilibrium states are determined with the C80 calorimeter (Setaram) equipped with membrane mixing cells at 313.15 K and atmospheric pressure. The quaternary system exhibited positive values of the excess enthalpies over the entire range of mole fractions. The heat of esterification reaction is calculated on the base of data obtained for heat effects in the mixture, and it was found to be − 3.6 ± 0.2 kJ mol−1. The correlation of the data was carried out using NRTL model and Redlich–Kister equation.",
keywords = "Calorimetry, Excess enthalpy, Heat of esterification reaction, Thermochemistry, N-PROPYL ACETATE, HYDROLYSIS, CRITICAL STATES, SOLUBILITY, CHEMICAL-EQUILIBRIUM, STANDARD MOLAR ENTHALPY, BINARY-MIXTURES, ALCOHOL, LIQUID-LIQUID EQUILIBRIUM, PROPANOL",
author = "Alexandra Golikova and Nikita Tsvetov and Artemiy Samarov and Maria Toikka and Irina Zvereva and Maya Trofimova and Alexander Toikka",
note = "Golikova, A., Tsvetov, N., Samarov, A. et al. Excess enthalpies and heat of esterification reaction in ethanol + acetic acid + ethyl acetate + water system at 313.15 K. J Therm Anal Calorim 139, 1301–1307 (2020). https://doi.org/10.1007/s10973-019-08488-y",
year = "2020",
month = jan,
doi = "10.1007/s10973-019-08488-y",
language = "English",
volume = "139",
pages = "1301--1307",
journal = "Journal of Thermal Analysis and Calorimetry",
issn = "1388-6150",
publisher = "Springer Nature",
number = "2",

}

RIS

TY - JOUR

T1 - Excess enthalpies and heat of esterification reaction in ethanol plus acetic acid plus ethyl acetate plus water system at 313.15 K

AU - Golikova, Alexandra

AU - Tsvetov, Nikita

AU - Samarov, Artemiy

AU - Toikka, Maria

AU - Zvereva, Irina

AU - Trofimova, Maya

AU - Toikka, Alexander

N1 - Golikova, A., Tsvetov, N., Samarov, A. et al. Excess enthalpies and heat of esterification reaction in ethanol + acetic acid + ethyl acetate + water system at 313.15 K. J Therm Anal Calorim 139, 1301–1307 (2020). https://doi.org/10.1007/s10973-019-08488-y

PY - 2020/1

Y1 - 2020/1

N2 - The excess enthalpies for ethanol + acetic acid + ethyl acetate + water system in the chemically equilibrium states are determined with the C80 calorimeter (Setaram) equipped with membrane mixing cells at 313.15 K and atmospheric pressure. The quaternary system exhibited positive values of the excess enthalpies over the entire range of mole fractions. The heat of esterification reaction is calculated on the base of data obtained for heat effects in the mixture, and it was found to be − 3.6 ± 0.2 kJ mol−1. The correlation of the data was carried out using NRTL model and Redlich–Kister equation.

AB - The excess enthalpies for ethanol + acetic acid + ethyl acetate + water system in the chemically equilibrium states are determined with the C80 calorimeter (Setaram) equipped with membrane mixing cells at 313.15 K and atmospheric pressure. The quaternary system exhibited positive values of the excess enthalpies over the entire range of mole fractions. The heat of esterification reaction is calculated on the base of data obtained for heat effects in the mixture, and it was found to be − 3.6 ± 0.2 kJ mol−1. The correlation of the data was carried out using NRTL model and Redlich–Kister equation.

KW - Calorimetry

KW - Excess enthalpy

KW - Heat of esterification reaction

KW - Thermochemistry

KW - N-PROPYL ACETATE

KW - HYDROLYSIS

KW - CRITICAL STATES

KW - SOLUBILITY

KW - CHEMICAL-EQUILIBRIUM

KW - STANDARD MOLAR ENTHALPY

KW - BINARY-MIXTURES

KW - ALCOHOL

KW - LIQUID-LIQUID EQUILIBRIUM

KW - PROPANOL

UR - http://www.scopus.com/inward/record.url?scp=85068189216&partnerID=8YFLogxK

U2 - 10.1007/s10973-019-08488-y

DO - 10.1007/s10973-019-08488-y

M3 - Article

AN - SCOPUS:85068189216

VL - 139

SP - 1301

EP - 1307

JO - Journal of Thermal Analysis and Calorimetry

JF - Journal of Thermal Analysis and Calorimetry

SN - 1388-6150

IS - 2

ER -

ID: 45870863