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Exact low-order classical moments in collision-induced bands by linear rotors: CO2-CO2. / Chrysos, M.; Kouzov, A. P.; Egorova, N. I.; Rachet, F.

в: Physical Review Letters, Том 100, № 13, 133007 , 04.04.2008.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Chrysos, M, Kouzov, AP, Egorova, NI & Rachet, F 2008, 'Exact low-order classical moments in collision-induced bands by linear rotors: CO2-CO2', Physical Review Letters, Том. 100, № 13, 133007 . https://doi.org/10.1103/PhysRevLett.100.133007

APA

Chrysos, M., Kouzov, A. P., Egorova, N. I., & Rachet, F. (2008). Exact low-order classical moments in collision-induced bands by linear rotors: CO2-CO2. Physical Review Letters, 100(13), [133007 ]. https://doi.org/10.1103/PhysRevLett.100.133007

Vancouver

Chrysos M, Kouzov AP, Egorova NI, Rachet F. Exact low-order classical moments in collision-induced bands by linear rotors: CO2-CO2. Physical Review Letters. 2008 Апр. 4;100(13). 133007 . https://doi.org/10.1103/PhysRevLett.100.133007

Author

Chrysos, M. ; Kouzov, A. P. ; Egorova, N. I. ; Rachet, F. / Exact low-order classical moments in collision-induced bands by linear rotors: CO2-CO2. в: Physical Review Letters. 2008 ; Том 100, № 13.

BibTeX

@article{0566554ac13f4d8f81a1ebcf303c1920,
title = "Exact low-order classical moments in collision-induced bands by linear rotors: CO2-CO2",
abstract = "Exact and general analytic expressions are reported for the integrated intensity and the width of collision-induced absorption (CIA) and collision-induced scattering (CIS) bands by gases of centrosymmetric linear molecules. These expressions provide significant insight and allow assignment of partial second moments to the degrees of freedom of the colliding molecules. The expressions are applied to ambient CO2, whose collisional spectra are reputed to be useful probes for terrestrial and planetary atmospheres. Compelling evidence of the substantial role of hitherto missing polarization and polarizability mechanisms is provided and is in remarkable agreement with experimental observation. Our findings allow the long-overdue simple interpretation of CIA and CIS by CO2-CO2 without the need to resort to short-range interactions to offset the discrepancies between theory and experiment. {\textcopyright} 2008 The American Physical Society.",
author = "M. Chrysos and Kouzov, {A. P.} and Egorova, {N. I.} and F. Rachet",
year = "2008",
month = apr,
day = "4",
doi = "10.1103/PhysRevLett.100.133007",
language = "English",
volume = "100",
journal = "Physical Review Letters",
issn = "0031-9007",
publisher = "American Physical Society",
number = "13",

}

RIS

TY - JOUR

T1 - Exact low-order classical moments in collision-induced bands by linear rotors: CO2-CO2

AU - Chrysos, M.

AU - Kouzov, A. P.

AU - Egorova, N. I.

AU - Rachet, F.

PY - 2008/4/4

Y1 - 2008/4/4

N2 - Exact and general analytic expressions are reported for the integrated intensity and the width of collision-induced absorption (CIA) and collision-induced scattering (CIS) bands by gases of centrosymmetric linear molecules. These expressions provide significant insight and allow assignment of partial second moments to the degrees of freedom of the colliding molecules. The expressions are applied to ambient CO2, whose collisional spectra are reputed to be useful probes for terrestrial and planetary atmospheres. Compelling evidence of the substantial role of hitherto missing polarization and polarizability mechanisms is provided and is in remarkable agreement with experimental observation. Our findings allow the long-overdue simple interpretation of CIA and CIS by CO2-CO2 without the need to resort to short-range interactions to offset the discrepancies between theory and experiment. © 2008 The American Physical Society.

AB - Exact and general analytic expressions are reported for the integrated intensity and the width of collision-induced absorption (CIA) and collision-induced scattering (CIS) bands by gases of centrosymmetric linear molecules. These expressions provide significant insight and allow assignment of partial second moments to the degrees of freedom of the colliding molecules. The expressions are applied to ambient CO2, whose collisional spectra are reputed to be useful probes for terrestrial and planetary atmospheres. Compelling evidence of the substantial role of hitherto missing polarization and polarizability mechanisms is provided and is in remarkable agreement with experimental observation. Our findings allow the long-overdue simple interpretation of CIA and CIS by CO2-CO2 without the need to resort to short-range interactions to offset the discrepancies between theory and experiment. © 2008 The American Physical Society.

UR - http://www.scopus.com/inward/record.url?scp=41849142285&partnerID=8YFLogxK

U2 - 10.1103/PhysRevLett.100.133007

DO - 10.1103/PhysRevLett.100.133007

M3 - Article

AN - SCOPUS:41849142285

VL - 100

JO - Physical Review Letters

JF - Physical Review Letters

SN - 0031-9007

IS - 13

M1 - 133007

ER -

ID: 104350402