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Evaluation of crosslinked cellulose-based solid and gel polymer electrolytes in lithium-ion batteries. / Safavi-Mirmahalleh, S.-A.; N Eliseeva, S.; Rezvani-Moghaddam, A.; Roghani-Mamaqani, H.; Salami-Kalajahi, M.

в: International Journal of Biological Macromolecules, Том 327, 06.09.2025.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Safavi-Mirmahalleh, S-A, N Eliseeva, S, Rezvani-Moghaddam, A, Roghani-Mamaqani, H & Salami-Kalajahi, M 2025, 'Evaluation of crosslinked cellulose-based solid and gel polymer electrolytes in lithium-ion batteries', International Journal of Biological Macromolecules, Том. 327. https://doi.org/10.1016/j.ijbiomac.2025.147508

APA

Safavi-Mirmahalleh, S-A., N Eliseeva, S., Rezvani-Moghaddam, A., Roghani-Mamaqani, H., & Salami-Kalajahi, M. (2025). Evaluation of crosslinked cellulose-based solid and gel polymer electrolytes in lithium-ion batteries. International Journal of Biological Macromolecules, 327. https://doi.org/10.1016/j.ijbiomac.2025.147508

Vancouver

Safavi-Mirmahalleh S-A, N Eliseeva S, Rezvani-Moghaddam A, Roghani-Mamaqani H, Salami-Kalajahi M. Evaluation of crosslinked cellulose-based solid and gel polymer electrolytes in lithium-ion batteries. International Journal of Biological Macromolecules. 2025 Сент. 6;327. https://doi.org/10.1016/j.ijbiomac.2025.147508

Author

Safavi-Mirmahalleh, S.-A. ; N Eliseeva, S. ; Rezvani-Moghaddam, A. ; Roghani-Mamaqani, H. ; Salami-Kalajahi, M. / Evaluation of crosslinked cellulose-based solid and gel polymer electrolytes in lithium-ion batteries. в: International Journal of Biological Macromolecules. 2025 ; Том 327.

BibTeX

@article{941808ce98f7423987726d2f547fce68,
title = "Evaluation of crosslinked cellulose-based solid and gel polymer electrolytes in lithium-ion batteries",
abstract = "In order to develop an alternate material for energy storage devices like batteries, this research is being done to create polymer electrolytes based on cellulose as natural polymer. Natural polymers as battery components have a number of advantages, including availability, biodegradability, unleakage, stable form, superior process, electrochemical stability, and low cost. In this study, polymer electrolytes based on cellulose have been synthesized by solution casting to prepare a thin polymer films. The solid or gel state of the polymer electrolyte and the kind of cross-linker (citric acid and polyvinyl alcohol) on the electrochemical properties of electrolyte have been investigated. Results showed that the crosslinking has improved ionic conductivity of solid and gel polymer electrolytes. Gel polymer electrolyte (GPE) cross-linked by 1 % citric acid exhibited higher ionic conductivities (up to 5.58 × 10−4 S cm−1 at room temperature) than other polymer electrolytes. The corresponding GPE presented a high lithium-ion transference number of 0.65, high electrochemical stability, and good specific capacity (212.41 mAh g−1 at 0.2C of LiCoO2/GPE-Ce-CA1/graphite). All these features prove that the GPE-Ce-CA1/graphite has great potential for the application of lithium-ion batteries. {\textcopyright} 2025 Elsevier B.V., All rights reserved.",
keywords = "Cellulose, Citric acid, Gel polymer electrolyte, Lithium-ion battery, Poly(vinyl alcohol), Solid polymer electrolyte, Cerium compounds, Crosslinking, Ionic conduction in solids, Ionic conductivity, Ions, Lithium compounds, Solid electrolytes, Thin film lithium ion batteries, Virtual storage, Electrochemical stabilities, Gel polymer electrolytes, Ion batteries, Lithium ions, Poly (vinyl alcohol) (PVA), Poly(vinyl alcohol) (PVA), Polymer electrolyte, Solid polymer electrolytes, cellulose, citric acid, electrolyte, gel, lithium ion, polymer, ion, lithium, Article, biodegradability, chronoamperometry, cross linking, crystal structure, cyclic voltammetry, electrochemical analysis, esterification, field emission scanning electron microscopy, hydrogen bond, impedance, polarization, temperature, thermogravimetry, water absorption, X ray diffraction, chemistry, electric conductivity, power supply, Cerium Compounds, Citric Acid, Electrolytes, Gels, Lithium Compounds, Solids, Electric Conductivity, Electric Power Supplies, Lithium, Polymers",
author = "S.-A. Safavi-Mirmahalleh and {N Eliseeva}, S. and A. Rezvani-Moghaddam and H. Roghani-Mamaqani and M. Salami-Kalajahi",
note = "Export Date: 01 November 2025; Cited By: 0; Correspondence Address: M. Salami-Kalajahi; Faculty of Polymer Engineering, Sahand University of Technology, Tabriz, P.O. Box 51335-1996, Iran; email: m.salami@sut.ac.ir; CODEN: IJBMD",
year = "2025",
month = sep,
day = "6",
doi = "10.1016/j.ijbiomac.2025.147508",
language = "English",
volume = "327",
journal = "International Journal of Biological Macromolecules",
issn = "0141-8130",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Evaluation of crosslinked cellulose-based solid and gel polymer electrolytes in lithium-ion batteries

AU - Safavi-Mirmahalleh, S.-A.

AU - N Eliseeva, S.

AU - Rezvani-Moghaddam, A.

AU - Roghani-Mamaqani, H.

AU - Salami-Kalajahi, M.

N1 - Export Date: 01 November 2025; Cited By: 0; Correspondence Address: M. Salami-Kalajahi; Faculty of Polymer Engineering, Sahand University of Technology, Tabriz, P.O. Box 51335-1996, Iran; email: m.salami@sut.ac.ir; CODEN: IJBMD

PY - 2025/9/6

Y1 - 2025/9/6

N2 - In order to develop an alternate material for energy storage devices like batteries, this research is being done to create polymer electrolytes based on cellulose as natural polymer. Natural polymers as battery components have a number of advantages, including availability, biodegradability, unleakage, stable form, superior process, electrochemical stability, and low cost. In this study, polymer electrolytes based on cellulose have been synthesized by solution casting to prepare a thin polymer films. The solid or gel state of the polymer electrolyte and the kind of cross-linker (citric acid and polyvinyl alcohol) on the electrochemical properties of electrolyte have been investigated. Results showed that the crosslinking has improved ionic conductivity of solid and gel polymer electrolytes. Gel polymer electrolyte (GPE) cross-linked by 1 % citric acid exhibited higher ionic conductivities (up to 5.58 × 10−4 S cm−1 at room temperature) than other polymer electrolytes. The corresponding GPE presented a high lithium-ion transference number of 0.65, high electrochemical stability, and good specific capacity (212.41 mAh g−1 at 0.2C of LiCoO2/GPE-Ce-CA1/graphite). All these features prove that the GPE-Ce-CA1/graphite has great potential for the application of lithium-ion batteries. © 2025 Elsevier B.V., All rights reserved.

AB - In order to develop an alternate material for energy storage devices like batteries, this research is being done to create polymer electrolytes based on cellulose as natural polymer. Natural polymers as battery components have a number of advantages, including availability, biodegradability, unleakage, stable form, superior process, electrochemical stability, and low cost. In this study, polymer electrolytes based on cellulose have been synthesized by solution casting to prepare a thin polymer films. The solid or gel state of the polymer electrolyte and the kind of cross-linker (citric acid and polyvinyl alcohol) on the electrochemical properties of electrolyte have been investigated. Results showed that the crosslinking has improved ionic conductivity of solid and gel polymer electrolytes. Gel polymer electrolyte (GPE) cross-linked by 1 % citric acid exhibited higher ionic conductivities (up to 5.58 × 10−4 S cm−1 at room temperature) than other polymer electrolytes. The corresponding GPE presented a high lithium-ion transference number of 0.65, high electrochemical stability, and good specific capacity (212.41 mAh g−1 at 0.2C of LiCoO2/GPE-Ce-CA1/graphite). All these features prove that the GPE-Ce-CA1/graphite has great potential for the application of lithium-ion batteries. © 2025 Elsevier B.V., All rights reserved.

KW - Cellulose

KW - Citric acid

KW - Gel polymer electrolyte

KW - Lithium-ion battery

KW - Poly(vinyl alcohol)

KW - Solid polymer electrolyte

KW - Cerium compounds

KW - Crosslinking

KW - Ionic conduction in solids

KW - Ionic conductivity

KW - Ions

KW - Lithium compounds

KW - Solid electrolytes

KW - Thin film lithium ion batteries

KW - Virtual storage

KW - Electrochemical stabilities

KW - Gel polymer electrolytes

KW - Ion batteries

KW - Lithium ions

KW - Poly (vinyl alcohol) (PVA)

KW - Poly(vinyl alcohol) (PVA)

KW - Polymer electrolyte

KW - Solid polymer electrolytes

KW - cellulose

KW - citric acid

KW - electrolyte

KW - gel

KW - lithium ion

KW - polymer

KW - ion

KW - lithium

KW - Article

KW - biodegradability

KW - chronoamperometry

KW - cross linking

KW - crystal structure

KW - cyclic voltammetry

KW - electrochemical analysis

KW - esterification

KW - field emission scanning electron microscopy

KW - hydrogen bond

KW - impedance

KW - polarization

KW - temperature

KW - thermogravimetry

KW - water absorption

KW - X ray diffraction

KW - chemistry

KW - electric conductivity

KW - power supply

KW - Cerium Compounds

KW - Citric Acid

KW - Electrolytes

KW - Gels

KW - Lithium Compounds

KW - Solids

KW - Electric Conductivity

KW - Electric Power Supplies

KW - Lithium

KW - Polymers

UR - https://www.mendeley.com/catalogue/73ad2b09-065f-3eba-9992-8303c8c7725a/

U2 - 10.1016/j.ijbiomac.2025.147508

DO - 10.1016/j.ijbiomac.2025.147508

M3 - Article

VL - 327

JO - International Journal of Biological Macromolecules

JF - International Journal of Biological Macromolecules

SN - 0141-8130

ER -

ID: 143731428