DOI

The excluded volume to be a key to deriving an equation of state was shown. Pressure and excluded volume were interrelated as an integral and an integrand, the former being less and the latter more sensitive to errors. Within the frame of the second approximation of the excluded volume theory, a sufficiently accurate three-term equation of state covering a wide density range was derived. Since the criterion of simplicity was used, the appraoch described can be modified by using other criteria.

Язык оригиналаанглийский
Страницы (с-по)10157-10163
Число страниц7
ЖурналJournal of Chemical Physics
Том118
Номер выпуска22
DOI
СостояниеОпубликовано - 8 июн 2003

    Предметные области Scopus

  • Физика и астрономия (все)
  • Физическая и теоретическая химия

ID: 95717199