Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Electrophysical properties of materials based on BaGdCo2O 5 + δ. / Medvedev, D. A.; Zhuravleva, T. A.; Murashkina, A. A.; Sergeeva, V. S.; Antonov, B. D.
в: Russian Journal of Physical Chemistry A, Том 84, № 9, 09.2010, стр. 1623-1627.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Electrophysical properties of materials based on BaGdCo2O 5 + δ
AU - Medvedev, D. A.
AU - Zhuravleva, T. A.
AU - Murashkina, A. A.
AU - Sergeeva, V. S.
AU - Antonov, B. D.
N1 - Funding Information: experiments with us. This work was supported by the Russian Foundation for Basic Research, grant no. 09 03 00181.
PY - 2010/9
Y1 - 2010/9
N2 - The phase composition, linear thermal expansion coefficient, electroconductivity (in the temperature interval 600-900°C and partial pressures of oxygen 10-5-0.21 atm) of solid-oxide materials based on gadolinium-barium cobaltite doped with 3d-elements BaGdCo2 - x Me x O5 + δ, Me = Cu, Fe; x = 0.0, 0.2, ⋯, 2.0 were investigated. The homogeneity regions of samples were established by means of X-ray phase analysis. It was shown that the linear thermal expansion coefficient of cobaltite decreases with an increase in the copper or iron concentration. It was established that the electroconductivity of BaGdCo 2 - x Me x O5 + δ decreases with an increase in x. We concluded that upon a decrease in p(O2), the electroconductivity of samples first decreases and then reaches a horizontal plateau.
AB - The phase composition, linear thermal expansion coefficient, electroconductivity (in the temperature interval 600-900°C and partial pressures of oxygen 10-5-0.21 atm) of solid-oxide materials based on gadolinium-barium cobaltite doped with 3d-elements BaGdCo2 - x Me x O5 + δ, Me = Cu, Fe; x = 0.0, 0.2, ⋯, 2.0 were investigated. The homogeneity regions of samples were established by means of X-ray phase analysis. It was shown that the linear thermal expansion coefficient of cobaltite decreases with an increase in the copper or iron concentration. It was established that the electroconductivity of BaGdCo 2 - x Me x O5 + δ decreases with an increase in x. We concluded that upon a decrease in p(O2), the electroconductivity of samples first decreases and then reaches a horizontal plateau.
UR - http://www.scopus.com/inward/record.url?scp=77956386363&partnerID=8YFLogxK
U2 - 10.1134/S0036024410090311
DO - 10.1134/S0036024410090311
M3 - Article
AN - SCOPUS:77956386363
VL - 84
SP - 1623
EP - 1627
JO - Russian Journal of Physical Chemistry A
JF - Russian Journal of Physical Chemistry A
SN - 0036-0244
IS - 9
ER -
ID: 85232244