Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Electronic effect of substituents in coupling reactions between para-substituted benzamidoximes and nitrile ligands in cis-[PtCl2(EtCN)2] complex. / Burianova, V.K.; Bolotin, D.S.
в: Russian Journal of General Chemistry, Том 85, № 12, 2015, стр. 2721-2724.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Electronic effect of substituents in coupling reactions between para-substituted benzamidoximes and nitrile ligands in cis-[PtCl2(EtCN)2] complex
AU - Burianova, V.K.
AU - Bolotin, D.S.
PY - 2015
Y1 - 2015
N2 - © 2015 Pleiades Publishing, Ltd.The rate constants were determined for a number of reactions of nucleophilic addition of para-substituted benzamidoximes 4-RC6H4C(NH2)=NOH to cis-[PtCl2(EtCN)2] at 23°C in acetone. A linear correlation between log (k R/k H) and σ para was found, and reaction constant ρ296(σ para ) was calculated. The prepared compounds were characterized by IR, 1H NMR, and HR ESI+-MS.
AB - © 2015 Pleiades Publishing, Ltd.The rate constants were determined for a number of reactions of nucleophilic addition of para-substituted benzamidoximes 4-RC6H4C(NH2)=NOH to cis-[PtCl2(EtCN)2] at 23°C in acetone. A linear correlation between log (k R/k H) and σ para was found, and reaction constant ρ296(σ para ) was calculated. The prepared compounds were characterized by IR, 1H NMR, and HR ESI+-MS.
U2 - 10.1134/S1070363215120099
DO - 10.1134/S1070363215120099
M3 - Article
VL - 85
SP - 2721
EP - 2724
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 12
ER -
ID: 3992891