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Electronic Branching Ratios of Spontaneous Emission for Transitions between States of the 3d and 2p Singlet Complexes of Terms of H2. / Astashkevich, S. A.; Kalachev, M. V.; Lavrov, B. P.

в: Optics and Spectroscopy (English translation of Optika i Spektroskopiya), Том 90, № 4, 01.04.2001, стр. 484-492.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Astashkevich, SA, Kalachev, MV & Lavrov, BP 2001, 'Electronic Branching Ratios of Spontaneous Emission for Transitions between States of the 3d and 2p Singlet Complexes of Terms of H2', Optics and Spectroscopy (English translation of Optika i Spektroskopiya), Том. 90, № 4, стр. 484-492. https://doi.org/10.1134/1.1366739

APA

Astashkevich, S. A., Kalachev, M. V., & Lavrov, B. P. (2001). Electronic Branching Ratios of Spontaneous Emission for Transitions between States of the 3d and 2p Singlet Complexes of Terms of H2. Optics and Spectroscopy (English translation of Optika i Spektroskopiya), 90(4), 484-492. https://doi.org/10.1134/1.1366739

Vancouver

Astashkevich SA, Kalachev MV, Lavrov BP. Electronic Branching Ratios of Spontaneous Emission for Transitions between States of the 3d and 2p Singlet Complexes of Terms of H2. Optics and Spectroscopy (English translation of Optika i Spektroskopiya). 2001 Апр. 1;90(4):484-492. https://doi.org/10.1134/1.1366739

Author

Astashkevich, S. A. ; Kalachev, M. V. ; Lavrov, B. P. / Electronic Branching Ratios of Spontaneous Emission for Transitions between States of the 3d and 2p Singlet Complexes of Terms of H2. в: Optics and Spectroscopy (English translation of Optika i Spektroskopiya). 2001 ; Том 90, № 4. стр. 484-492.

BibTeX

@article{2ef8b56b4d934c258b76b31871f14d23,
title = "Electronic Branching Ratios of Spontaneous Emission for Transitions between States of the 3d and 2p Singlet Complexes of Terms of H2",
abstract = "The ratios of probabilities (the electronic branching ratios) for the rovibronic spontaneous transitions are for the first time measured for transitions from the rotational levels with J′ ≤ 6 of the I 1∏g -,v′ = 0-2 and J 1δg -, v′ = 0 states to the vibrational-rotational levels of different low-lying electronic states B 1∑u +, v″, J′ and C 1∏u -, v‴, J′ - 1 of the H2 molecule (for the vibrational quantum numbers v″ ≤ 4 and v‴ ≤ 2). Values of these quantities provide a new channel of information on the internal structure of the hydrogen molecule thus far unused and should be particularly sensitive to the adiabatic values of the electronic transition dipole moments. In studying the entire set of rovibronic radiative transitions, they may significantly add to the experimental data on rovibronic terms, radiative lifetimes, and vibrational and rotational branching ratios used before. The experimental data obtained are compared to the corresponding values derived from the results of an earlier semiempirical determination and ab initio calculation of the absolute transition probabilities. Our experimental data are in remarkable agreement with the semiempirical results and significantly differ from the ab initio results. This fact directly suggests the necessity of performing more accurate ab initio calculations of the rovibronic transition probabilities for the given systems of bands.",
author = "Astashkevich, {S. A.} and Kalachev, {M. V.} and Lavrov, {B. P.}",
year = "2001",
month = apr,
day = "1",
doi = "10.1134/1.1366739",
language = "English",
volume = "90",
pages = "484--492",
journal = "OPTICS AND SPECTROSCOPY",
issn = "0030-400X",
publisher = "Pleiades Publishing",
number = "4",

}

RIS

TY - JOUR

T1 - Electronic Branching Ratios of Spontaneous Emission for Transitions between States of the 3d and 2p Singlet Complexes of Terms of H2

AU - Astashkevich, S. A.

AU - Kalachev, M. V.

AU - Lavrov, B. P.

PY - 2001/4/1

Y1 - 2001/4/1

N2 - The ratios of probabilities (the electronic branching ratios) for the rovibronic spontaneous transitions are for the first time measured for transitions from the rotational levels with J′ ≤ 6 of the I 1∏g -,v′ = 0-2 and J 1δg -, v′ = 0 states to the vibrational-rotational levels of different low-lying electronic states B 1∑u +, v″, J′ and C 1∏u -, v‴, J′ - 1 of the H2 molecule (for the vibrational quantum numbers v″ ≤ 4 and v‴ ≤ 2). Values of these quantities provide a new channel of information on the internal structure of the hydrogen molecule thus far unused and should be particularly sensitive to the adiabatic values of the electronic transition dipole moments. In studying the entire set of rovibronic radiative transitions, they may significantly add to the experimental data on rovibronic terms, radiative lifetimes, and vibrational and rotational branching ratios used before. The experimental data obtained are compared to the corresponding values derived from the results of an earlier semiempirical determination and ab initio calculation of the absolute transition probabilities. Our experimental data are in remarkable agreement with the semiempirical results and significantly differ from the ab initio results. This fact directly suggests the necessity of performing more accurate ab initio calculations of the rovibronic transition probabilities for the given systems of bands.

AB - The ratios of probabilities (the electronic branching ratios) for the rovibronic spontaneous transitions are for the first time measured for transitions from the rotational levels with J′ ≤ 6 of the I 1∏g -,v′ = 0-2 and J 1δg -, v′ = 0 states to the vibrational-rotational levels of different low-lying electronic states B 1∑u +, v″, J′ and C 1∏u -, v‴, J′ - 1 of the H2 molecule (for the vibrational quantum numbers v″ ≤ 4 and v‴ ≤ 2). Values of these quantities provide a new channel of information on the internal structure of the hydrogen molecule thus far unused and should be particularly sensitive to the adiabatic values of the electronic transition dipole moments. In studying the entire set of rovibronic radiative transitions, they may significantly add to the experimental data on rovibronic terms, radiative lifetimes, and vibrational and rotational branching ratios used before. The experimental data obtained are compared to the corresponding values derived from the results of an earlier semiempirical determination and ab initio calculation of the absolute transition probabilities. Our experimental data are in remarkable agreement with the semiempirical results and significantly differ from the ab initio results. This fact directly suggests the necessity of performing more accurate ab initio calculations of the rovibronic transition probabilities for the given systems of bands.

UR - http://www.scopus.com/inward/record.url?scp=0141673601&partnerID=8YFLogxK

U2 - 10.1134/1.1366739

DO - 10.1134/1.1366739

M3 - Article

AN - SCOPUS:0141673601

VL - 90

SP - 484

EP - 492

JO - OPTICS AND SPECTROSCOPY

JF - OPTICS AND SPECTROSCOPY

SN - 0030-400X

IS - 4

ER -

ID: 33268449