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The scaling of nuclear-spin-dependent parity-violating effects with increasing nuclear charge Z is discussed in two series of isoelectronic open-shell diatomic molecules. The parameter Wa characterizing the strength of parity violation in diatomic molecules is calculated in the framework of the zeroth-order regular approximation and found to be in good agreement with the R(Z)Zk scaling law derived for atoms, in which R(Z) represents a relativistic enhancement factor. The influence of electron correlation is studied on the molecular level, with spin-polarization effects being conveniently accounted for by a previously established approximate relation between the hyperfine coupling tensor and Wa. For high-accuracy predictions of parity-violating effects in radium fluoride, the necessity for systematically improvable correlation calculations is emphasized.
Язык оригинала | английский |
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Номер статьи | 062515 |
Журнал | Physical Review A - Atomic, Molecular, and Optical Physics |
Том | 86 |
Номер выпуска | 6 |
DOI | |
Состояние | Опубликовано - 27 дек 2012 |
Опубликовано для внешнего пользования | Да |
ID: 11796670