Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Electrical properties of Ni-doped CaCu3Ti4O12 ceramics. / Zhuk, N. A.; Sekushin, N. A.; Krzhizhanovskaya, M. G.; Belyy, V. A.; Korolev, R. I.
в: Solid State Ionics, Том 364, 115633, 01.06.2021.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Electrical properties of Ni-doped CaCu3Ti4O12 ceramics
AU - Zhuk, N. A.
AU - Sekushin, N. A.
AU - Krzhizhanovskaya, M. G.
AU - Belyy, V. A.
AU - Korolev, R. I.
N1 - Publisher Copyright: © 2021 Elsevier B.V.
PY - 2021/6/1
Y1 - 2021/6/1
N2 - Samples of Ni-doped CaCu3Ti4O12 ceramics with the compositions of CaCu3Ti4-4хNi4хO12-δ and CaCu3-3хNi3хTi4O12 (x ≤ 0.06) were synthesized by the solid phase method. X-ray phase analysis revealed the trace amounts of copper oxide (II) admixture in the samples. Electrical properties of the samples of both compositions were studied in the temperature range of 25–400°С. The minimal dielectric loss tangent 0.07 and the maximal dielectric constant 6.0·103 (at 1 MHz) were exhibited by the CaCu3Ti4-4хNi4хO12-δ (х = 0.03) ceramics at room temperature. The equivalent circuit was created based on the modeling of impedance spectra that well describe the electrical properties of the samples. It was proposed that the ionic charge transfer predominated in the studied samples at room temperature. This mechanism allows to explain the giant values of dielectric permeability and the high values of impedance phase at low frequencies. The electrical properties of Ni-doped CaCu3Ti4O12 ceramics were analyzed and discussed.
AB - Samples of Ni-doped CaCu3Ti4O12 ceramics with the compositions of CaCu3Ti4-4хNi4хO12-δ and CaCu3-3хNi3хTi4O12 (x ≤ 0.06) were synthesized by the solid phase method. X-ray phase analysis revealed the trace amounts of copper oxide (II) admixture in the samples. Electrical properties of the samples of both compositions were studied in the temperature range of 25–400°С. The minimal dielectric loss tangent 0.07 and the maximal dielectric constant 6.0·103 (at 1 MHz) were exhibited by the CaCu3Ti4-4хNi4хO12-δ (х = 0.03) ceramics at room temperature. The equivalent circuit was created based on the modeling of impedance spectra that well describe the electrical properties of the samples. It was proposed that the ionic charge transfer predominated in the studied samples at room temperature. This mechanism allows to explain the giant values of dielectric permeability and the high values of impedance phase at low frequencies. The electrical properties of Ni-doped CaCu3Ti4O12 ceramics were analyzed and discussed.
KW - Calcium‑copper titanate
KW - Dielectric loss tangent
KW - Dielectric permittivity
KW - Electrical characteristics
KW - Nickel
KW - MN
KW - SUBSTITUTION
KW - Calcium-copper titanate
KW - CONSTANT
KW - IMPEDANCE SPECTROSCOPY
KW - CRYSTAL
KW - RESPONSES
KW - DIELECTRIC-PROPERTIES
KW - MICROSTRUCTURE
UR - http://www.scopus.com/inward/record.url?scp=85105697285&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/47806625-6f73-374d-8b66-f67d82db910e/
U2 - 10.1016/j.ssi.2021.115633
DO - 10.1016/j.ssi.2021.115633
M3 - Article
AN - SCOPUS:85105697285
VL - 364
JO - Solid State Ionics
JF - Solid State Ionics
SN - 0167-2738
M1 - 115633
ER -
ID: 78887376