ELECTRIC POTENTIAL OF LIQUID ION-EXCHANGE MEMBRANES IN CONTACT WITH NOLUTIONS CONTAINING UNI- AND DIVALENT COUNTERIONS. THE NATURE OF ANOMALOUS RESPONSE.

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ELECTRIC POTENTIAL OF LIQUID ION-EXCHANGE MEMBRANES IN CONTACT WITH NOLUTIONS CONTAINING UNI- AND DIVALENT COUNTERIONS. THE NATURE OF ANOMALOUS RESPONSE. / Mikhel'son, K. N.

в: SOVIET ELECTROCHEMISTRY, Том 23, № 4, 04.1987, стр. 409-416.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{6f9b0e1de35c4286b01efd4d4b1ef124,

title = "ELECTRIC POTENTIAL OF LIQUID ION-EXCHANGE MEMBRANES IN CONTACT WITH NOLUTIONS CONTAINING UNI- AND DIVALENT COUNTERIONS. THE NATURE OF ANOMALOUS RESPONSE.",

abstract = "W. E. Morf's well-known equation for the electric potential of ion-exchange membranes is analyzed in solutions with uni- and divalent counterions. A generalization of this equation for the case of membranes with two sorts of ion exchanger is obtained. The nature of the 'anomalous' response (potential 'dip' and 'hyperfunction') is discussed. These anomalies are shown to arise from transport of the principal counterions from the interior to the surface of the membrane when the mobility of the exchanger ions is low and association between the exchanger ions and the secondary counterions penetrating the membrane is strong.",

author = "Mikhel'son, {K. N.}",

year = "1987",

month = apr,

language = "English",

volume = "23",

pages = "409--416",

journal = "Russian Journal of Electrochemistry",

issn = "1023-1935",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "4",

}

RIS

TY - JOUR

T1 - ELECTRIC POTENTIAL OF LIQUID ION-EXCHANGE MEMBRANES IN CONTACT WITH NOLUTIONS CONTAINING UNI- AND DIVALENT COUNTERIONS. THE NATURE OF ANOMALOUS RESPONSE.

AU - Mikhel'son, K. N.

PY - 1987/4

Y1 - 1987/4

N2 - W. E. Morf's well-known equation for the electric potential of ion-exchange membranes is analyzed in solutions with uni- and divalent counterions. A generalization of this equation for the case of membranes with two sorts of ion exchanger is obtained. The nature of the 'anomalous' response (potential 'dip' and 'hyperfunction') is discussed. These anomalies are shown to arise from transport of the principal counterions from the interior to the surface of the membrane when the mobility of the exchanger ions is low and association between the exchanger ions and the secondary counterions penetrating the membrane is strong.

AB - W. E. Morf's well-known equation for the electric potential of ion-exchange membranes is analyzed in solutions with uni- and divalent counterions. A generalization of this equation for the case of membranes with two sorts of ion exchanger is obtained. The nature of the 'anomalous' response (potential 'dip' and 'hyperfunction') is discussed. These anomalies are shown to arise from transport of the principal counterions from the interior to the surface of the membrane when the mobility of the exchanger ions is low and association between the exchanger ions and the secondary counterions penetrating the membrane is strong.

UR - http://www.scopus.com/inward/record.url?scp=0023325757&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0023325757

VL - 23

SP - 409

EP - 416

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

SN - 1023-1935

IS - 4

ER -

ID: 92361764