Standard

Electric birefringence of poly(butyl isocyanate) solutions in strong electric fields. / Rotinyan, T. A.; Lyulin, S. V.; Lezov, A. V.; Tsvetkov, N. V.; Neelov, I. M.; Yazikov, S. B.; Ryumtsev, E. I.; Gotlib, Yu Ya.

в: Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya, Том 44, № 10, 2002, стр. 1786-1790.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Rotinyan, TA, Lyulin, SV, Lezov, AV, Tsvetkov, NV, Neelov, IM, Yazikov, SB, Ryumtsev, EI & Gotlib, YY 2002, 'Electric birefringence of poly(butyl isocyanate) solutions in strong electric fields', Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya, Том. 44, № 10, стр. 1786-1790.

APA

Rotinyan, T. A., Lyulin, S. V., Lezov, A. V., Tsvetkov, N. V., Neelov, I. M., Yazikov, S. B., Ryumtsev, E. I., & Gotlib, Y. Y. (2002). Electric birefringence of poly(butyl isocyanate) solutions in strong electric fields. Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya, 44(10), 1786-1790.

Vancouver

Rotinyan TA, Lyulin SV, Lezov AV, Tsvetkov NV, Neelov IM, Yazikov SB и пр. Electric birefringence of poly(butyl isocyanate) solutions in strong electric fields. Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya. 2002;44(10):1786-1790.

Author

Rotinyan, T. A. ; Lyulin, S. V. ; Lezov, A. V. ; Tsvetkov, N. V. ; Neelov, I. M. ; Yazikov, S. B. ; Ryumtsev, E. I. ; Gotlib, Yu Ya. / Electric birefringence of poly(butyl isocyanate) solutions in strong electric fields. в: Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya. 2002 ; Том 44, № 10. стр. 1786-1790.

BibTeX

@article{a4fb172f48524afd8d9749546f4c0077,
title = "Electric birefringence of poly(butyl isocyanate) solutions in strong electric fields",
abstract = "Electric birefringence (EBF) was studied for solutions of a poly(butyl isocyanate) high-molecular-mass fraction (MDη = 770 × 103) in tetrachloromethane in strong fields. The deviation from the linear dependence of EBF on the squared field strength was revealed. The experimental dependence was compared with the theoretical relationships calculated for the rodlike, freely jointed, and rotational-isomer models of a chain. It was shown that the values of the statistical segment length and the dipole moment of the monomer unit obtained for the rotational isomeric state model of a polymer chain on the tetrahedral lattice are consistent with known experimental data. The experimental results obtained confirm the theoretical conclusion that the orientation of the rotational-isomer polymer chain with a constant longitudinal dipole moment is equivalent to that of the 'effective' freely jointed chain with the field-dependent length of the rigid segment. The length of the effective segment is close to the average length of the regular trans sequence of a polymer chain on the tetrahedral lattice.",
author = "Rotinyan, {T. A.} and Lyulin, {S. V.} and Lezov, {A. V.} and Tsvetkov, {N. V.} and Neelov, {I. M.} and Yazikov, {S. B.} and Ryumtsev, {E. I.} and Gotlib, {Yu Ya}",
year = "2002",
language = "English",
volume = "44",
pages = "1786--1790",
journal = "ВЫСОКОМОЛЕКУЛЯРНЫЕ СОЕДИНЕНИЯ. СЕРИЯ А",
issn = "2308-1120",
publisher = "Издательство {"}Наука{"}",
number = "10",

}

RIS

TY - JOUR

T1 - Electric birefringence of poly(butyl isocyanate) solutions in strong electric fields

AU - Rotinyan, T. A.

AU - Lyulin, S. V.

AU - Lezov, A. V.

AU - Tsvetkov, N. V.

AU - Neelov, I. M.

AU - Yazikov, S. B.

AU - Ryumtsev, E. I.

AU - Gotlib, Yu Ya

PY - 2002

Y1 - 2002

N2 - Electric birefringence (EBF) was studied for solutions of a poly(butyl isocyanate) high-molecular-mass fraction (MDη = 770 × 103) in tetrachloromethane in strong fields. The deviation from the linear dependence of EBF on the squared field strength was revealed. The experimental dependence was compared with the theoretical relationships calculated for the rodlike, freely jointed, and rotational-isomer models of a chain. It was shown that the values of the statistical segment length and the dipole moment of the monomer unit obtained for the rotational isomeric state model of a polymer chain on the tetrahedral lattice are consistent with known experimental data. The experimental results obtained confirm the theoretical conclusion that the orientation of the rotational-isomer polymer chain with a constant longitudinal dipole moment is equivalent to that of the 'effective' freely jointed chain with the field-dependent length of the rigid segment. The length of the effective segment is close to the average length of the regular trans sequence of a polymer chain on the tetrahedral lattice.

AB - Electric birefringence (EBF) was studied for solutions of a poly(butyl isocyanate) high-molecular-mass fraction (MDη = 770 × 103) in tetrachloromethane in strong fields. The deviation from the linear dependence of EBF on the squared field strength was revealed. The experimental dependence was compared with the theoretical relationships calculated for the rodlike, freely jointed, and rotational-isomer models of a chain. It was shown that the values of the statistical segment length and the dipole moment of the monomer unit obtained for the rotational isomeric state model of a polymer chain on the tetrahedral lattice are consistent with known experimental data. The experimental results obtained confirm the theoretical conclusion that the orientation of the rotational-isomer polymer chain with a constant longitudinal dipole moment is equivalent to that of the 'effective' freely jointed chain with the field-dependent length of the rigid segment. The length of the effective segment is close to the average length of the regular trans sequence of a polymer chain on the tetrahedral lattice.

UR - http://www.scopus.com/inward/record.url?scp=0036950116&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0036950116

VL - 44

SP - 1786

EP - 1790

JO - ВЫСОКОМОЛЕКУЛЯРНЫЕ СОЕДИНЕНИЯ. СЕРИЯ А

JF - ВЫСОКОМОЛЕКУЛЯРНЫЕ СОЕДИНЕНИЯ. СЕРИЯ А

SN - 2308-1120

IS - 10

ER -

ID: 94253619