Standard

Electric birefringence of poly(butyl isocyanate) solutions in strong electric fields. / Rotinyan, T. A.; Lyulin, S. V.; Lezov, A. V.; Tsvetkov, N. V.; Neelov, I. M.; Yazikov, S. B.; Ryumtsev, E. I.; Gotlib, Yu Ya.

в: Polymer Science - Series A, Том 44, № 10, 01.10.2002, стр. 1061-1064.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Rotinyan, TA, Lyulin, SV, Lezov, AV, Tsvetkov, NV, Neelov, IM, Yazikov, SB, Ryumtsev, EI & Gotlib, YY 2002, 'Electric birefringence of poly(butyl isocyanate) solutions in strong electric fields', Polymer Science - Series A, Том. 44, № 10, стр. 1061-1064.

APA

Rotinyan, T. A., Lyulin, S. V., Lezov, A. V., Tsvetkov, N. V., Neelov, I. M., Yazikov, S. B., Ryumtsev, E. I., & Gotlib, Y. Y. (2002). Electric birefringence of poly(butyl isocyanate) solutions in strong electric fields. Polymer Science - Series A, 44(10), 1061-1064.

Vancouver

Rotinyan TA, Lyulin SV, Lezov AV, Tsvetkov NV, Neelov IM, Yazikov SB и пр. Electric birefringence of poly(butyl isocyanate) solutions in strong electric fields. Polymer Science - Series A. 2002 Окт. 1;44(10):1061-1064.

Author

Rotinyan, T. A. ; Lyulin, S. V. ; Lezov, A. V. ; Tsvetkov, N. V. ; Neelov, I. M. ; Yazikov, S. B. ; Ryumtsev, E. I. ; Gotlib, Yu Ya. / Electric birefringence of poly(butyl isocyanate) solutions in strong electric fields. в: Polymer Science - Series A. 2002 ; Том 44, № 10. стр. 1061-1064.

BibTeX

@article{28d04028ca09450d9f3fbb0879ec5840,
title = "Electric birefringence of poly(butyl isocyanate) solutions in strong electric fields",
abstract = "Electric birefringence (EBF) was studied for solutions of a poly(butyl isocyanate) high-molecular-mass fraction (MDη = 770 × 103) in tetrachloromethane in strong fields. Deviation from the linear dependence of EBF on the squared field strength was revealed. The experimental dependence was compared with the theoretical relationships calculated for the rodlike, freely jointed, and rotational-isomer models of a chain. It was shown that the values of the statistical segment length and the dipole moment of the monomer unit obtained for the rotational isomeric state model of a polymer chain on the tetrahedral lattice are consistent with known experimental data. The experimental results obtained confirm the theoretical conclusion that the orientation of the rotational-isomer polymer chain with a constant longitudinal dipole moment is equivalent to that of the {"}effective{"} freely jointed chain with a field-dependent length of the rigid segment. The length of the effective segment is close to the average length of the regular trans sequence of a polymer chain on the tetrahedral lattice.",
author = "Rotinyan, {T. A.} and Lyulin, {S. V.} and Lezov, {A. V.} and Tsvetkov, {N. V.} and Neelov, {I. M.} and Yazikov, {S. B.} and Ryumtsev, {E. I.} and Gotlib, {Yu Ya}",
year = "2002",
month = oct,
day = "1",
language = "English",
volume = "44",
pages = "1061--1064",
journal = "Polymer Science - Series A",
issn = "0965-545X",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "10",

}

RIS

TY - JOUR

T1 - Electric birefringence of poly(butyl isocyanate) solutions in strong electric fields

AU - Rotinyan, T. A.

AU - Lyulin, S. V.

AU - Lezov, A. V.

AU - Tsvetkov, N. V.

AU - Neelov, I. M.

AU - Yazikov, S. B.

AU - Ryumtsev, E. I.

AU - Gotlib, Yu Ya

PY - 2002/10/1

Y1 - 2002/10/1

N2 - Electric birefringence (EBF) was studied for solutions of a poly(butyl isocyanate) high-molecular-mass fraction (MDη = 770 × 103) in tetrachloromethane in strong fields. Deviation from the linear dependence of EBF on the squared field strength was revealed. The experimental dependence was compared with the theoretical relationships calculated for the rodlike, freely jointed, and rotational-isomer models of a chain. It was shown that the values of the statistical segment length and the dipole moment of the monomer unit obtained for the rotational isomeric state model of a polymer chain on the tetrahedral lattice are consistent with known experimental data. The experimental results obtained confirm the theoretical conclusion that the orientation of the rotational-isomer polymer chain with a constant longitudinal dipole moment is equivalent to that of the "effective" freely jointed chain with a field-dependent length of the rigid segment. The length of the effective segment is close to the average length of the regular trans sequence of a polymer chain on the tetrahedral lattice.

AB - Electric birefringence (EBF) was studied for solutions of a poly(butyl isocyanate) high-molecular-mass fraction (MDη = 770 × 103) in tetrachloromethane in strong fields. Deviation from the linear dependence of EBF on the squared field strength was revealed. The experimental dependence was compared with the theoretical relationships calculated for the rodlike, freely jointed, and rotational-isomer models of a chain. It was shown that the values of the statistical segment length and the dipole moment of the monomer unit obtained for the rotational isomeric state model of a polymer chain on the tetrahedral lattice are consistent with known experimental data. The experimental results obtained confirm the theoretical conclusion that the orientation of the rotational-isomer polymer chain with a constant longitudinal dipole moment is equivalent to that of the "effective" freely jointed chain with a field-dependent length of the rigid segment. The length of the effective segment is close to the average length of the regular trans sequence of a polymer chain on the tetrahedral lattice.

UR - http://www.scopus.com/inward/record.url?scp=0036816153&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0036816153

VL - 44

SP - 1061

EP - 1064

JO - Polymer Science - Series A

JF - Polymer Science - Series A

SN - 0965-545X

IS - 10

ER -

ID: 94253821