Standard

Efficient scalar spin relaxation in the rotating frame for matched radio-frequency fields. / Skrynnikov, N. R.; Lienin, S. F.; Brüschweiler, R.; Ernst, R. R.

в: Journal of Chemical Physics, Том 108, № 18, 08.05.1998, стр. 7662-7669.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Skrynnikov, NR, Lienin, SF, Brüschweiler, R & Ernst, RR 1998, 'Efficient scalar spin relaxation in the rotating frame for matched radio-frequency fields', Journal of Chemical Physics, Том. 108, № 18, стр. 7662-7669. https://doi.org/10.1063/1.476202

APA

Skrynnikov, N. R., Lienin, S. F., Brüschweiler, R., & Ernst, R. R. (1998). Efficient scalar spin relaxation in the rotating frame for matched radio-frequency fields. Journal of Chemical Physics, 108(18), 7662-7669. https://doi.org/10.1063/1.476202

Vancouver

Skrynnikov NR, Lienin SF, Brüschweiler R, Ernst RR. Efficient scalar spin relaxation in the rotating frame for matched radio-frequency fields. Journal of Chemical Physics. 1998 Май 8;108(18):7662-7669. https://doi.org/10.1063/1.476202

Author

Skrynnikov, N. R. ; Lienin, S. F. ; Brüschweiler, R. ; Ernst, R. R. / Efficient scalar spin relaxation in the rotating frame for matched radio-frequency fields. в: Journal of Chemical Physics. 1998 ; Том 108, № 18. стр. 7662-7669.

BibTeX

@article{7a2e3ae3e59c40bfa1e93bbf9147bd06,
title = "Efficient scalar spin relaxation in the rotating frame for matched radio-frequency fields",
abstract = "A theoretical analysis is presented for liquid-state T1ρ relaxation in a coupled two-spin system I = 1/2, S=1 in the presence of two radio-frequency fields applied to each of the spins individually. It is demonstrated that the relaxation rate constant T1ρ-1 of the spin I due to scalar relaxation sharply increases when the two radio-frequency fields are matched according to the Hartmann-Hahn condition. Relaxation measurements on the amino-protons of 3-nitroaniline show good agreement with theory.",
author = "Skrynnikov, {N. R.} and Lienin, {S. F.} and R. Br{\"u}schweiler and Ernst, {R. R.}",
year = "1998",
month = may,
day = "8",
doi = "10.1063/1.476202",
language = "English",
volume = "108",
pages = "7662--7669",
journal = "Journal of Chemical Physics",
issn = "0021-9606",
publisher = "American Institute of Physics",
number = "18",

}

RIS

TY - JOUR

T1 - Efficient scalar spin relaxation in the rotating frame for matched radio-frequency fields

AU - Skrynnikov, N. R.

AU - Lienin, S. F.

AU - Brüschweiler, R.

AU - Ernst, R. R.

PY - 1998/5/8

Y1 - 1998/5/8

N2 - A theoretical analysis is presented for liquid-state T1ρ relaxation in a coupled two-spin system I = 1/2, S=1 in the presence of two radio-frequency fields applied to each of the spins individually. It is demonstrated that the relaxation rate constant T1ρ-1 of the spin I due to scalar relaxation sharply increases when the two radio-frequency fields are matched according to the Hartmann-Hahn condition. Relaxation measurements on the amino-protons of 3-nitroaniline show good agreement with theory.

AB - A theoretical analysis is presented for liquid-state T1ρ relaxation in a coupled two-spin system I = 1/2, S=1 in the presence of two radio-frequency fields applied to each of the spins individually. It is demonstrated that the relaxation rate constant T1ρ-1 of the spin I due to scalar relaxation sharply increases when the two radio-frequency fields are matched according to the Hartmann-Hahn condition. Relaxation measurements on the amino-protons of 3-nitroaniline show good agreement with theory.

UR - http://www.scopus.com/inward/record.url?scp=0347975739&partnerID=8YFLogxK

U2 - 10.1063/1.476202

DO - 10.1063/1.476202

M3 - Article

AN - SCOPUS:0347975739

VL - 108

SP - 7662

EP - 7669

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 18

ER -

ID: 87883580