Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Effect of preparation method on the valence state and encirclement of copper exchange ions in mordenites. / Zhukov, Y.M.; Efimov, A. Yu.; Shelyapina, M.G.; Petranovskii, V.; Zhizhin, E.V.; Burovikhina, A.; Zvereva, I.A.
в: Microporous and Mesoporous Materials, Том 224, 2016, стр. 1-5.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Effect of preparation method on the valence state and encirclement of copper exchange ions in mordenites
AU - Zhukov, Y.M.
AU - Efimov, A. Yu.
AU - Shelyapina, M.G.
AU - Petranovskii, V.
AU - Zhizhin, E.V.
AU - Burovikhina, A.
AU - Zvereva, I.A.
PY - 2016
Y1 - 2016
N2 - Samples of mordenites with variable Si/Al atomic ratio and different counter-ions were exchanged with copper ions by two methods e the conventional treatment in water solution and by microwave-assisted procedure. The zeolite-solution ratio and the concentration of solution were kept equal for both procedures. We report on the results of XRD, TGA and XPS studies. The XPS analysis confirms that despite observed differences in the spectra of the samples the copper ions are in the þ2 oxidation state. The preparation method influences copper and water content and copper surrounding, but does not change the electronic state of copper ions.
AB - Samples of mordenites with variable Si/Al atomic ratio and different counter-ions were exchanged with copper ions by two methods e the conventional treatment in water solution and by microwave-assisted procedure. The zeolite-solution ratio and the concentration of solution were kept equal for both procedures. We report on the results of XRD, TGA and XPS studies. The XPS analysis confirms that despite observed differences in the spectra of the samples the copper ions are in the þ2 oxidation state. The preparation method influences copper and water content and copper surrounding, but does not change the electronic state of copper ions.
KW - Copper exchanged zeolites
KW - Microwave assisted synthesis
KW - XPS
KW - TGA
M3 - Article
VL - 224
SP - 1
EP - 5
JO - Zeolites
JF - Zeolites
SN - 1387-1811
ER -
ID: 7552326