Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Effect of interparticle interactions on the rate of injection of charge carriers into electroactive polymer films. / Malev, V. V.; Levin, O. V.; Vorotyntsev, M. A.
в: Russian Journal of Electrochemistry, Том 43, № 9, 01.09.2007, стр. 1016-1025.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Effect of interparticle interactions on the rate of injection of charge carriers into electroactive polymer films
AU - Malev, V. V.
AU - Levin, O. V.
AU - Vorotyntsev, M. A.
PY - 2007/9/1
Y1 - 2007/9/1
N2 - A phenomenological approach is used for deriving a difference equation for the density of reduced sites in films of electroactive polymers with conspicuous interparticle interactions. The approach involves simultaneous application of the lattice methods and Broensted's rule. This leads to generalization of equations for the surface layer that are known in theory of surface tension for nonelectrolytic solutions. Together with the Poisson equation for electric potential, the derived relationships make a complicated system of differential equations. Nevertheless, it can be solved by iterative methods. In the framework of this approach, expressions for the rates of injection of charge carriers into polymer films are obtained. Within a first approximation with regard to allowance for the forces of short-range interactions, their influence on the rates of injection of electrons and protons into a film is discussed.
AB - A phenomenological approach is used for deriving a difference equation for the density of reduced sites in films of electroactive polymers with conspicuous interparticle interactions. The approach involves simultaneous application of the lattice methods and Broensted's rule. This leads to generalization of equations for the surface layer that are known in theory of surface tension for nonelectrolytic solutions. Together with the Poisson equation for electric potential, the derived relationships make a complicated system of differential equations. Nevertheless, it can be solved by iterative methods. In the framework of this approach, expressions for the rates of injection of charge carriers into polymer films are obtained. Within a first approximation with regard to allowance for the forces of short-range interactions, their influence on the rates of injection of electrons and protons into a film is discussed.
KW - Charge carrier
KW - Electroactive polymer
KW - Film
KW - Injection
KW - Interparticle interaction
KW - Model
UR - http://www.scopus.com/inward/record.url?scp=34848814100&partnerID=8YFLogxK
U2 - 10.1134/S1023193507090054
DO - 10.1134/S1023193507090054
M3 - Article
AN - SCOPUS:34848814100
VL - 43
SP - 1016
EP - 1025
JO - Russian Journal of Electrochemistry
JF - Russian Journal of Electrochemistry
SN - 1023-1935
IS - 9
ER -
ID: 36236392