Standard

Effect of draining of macromolecules on the results of size-exclusion chromatography measurements. / Vilenchik, L. Z.; Zhmakina, T. P.; Sklizkova, V. P.; Kudriavtsev, V. V.; Tennikova, T. B.; Belnikevich, N. G.; Belenkii, B. G.; Frenkel, S. Ya; Koton, M. M.

в: Chromatographia, Том 24, № 1, 12.1987, стр. 633-636.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Vilenchik, LZ, Zhmakina, TP, Sklizkova, VP, Kudriavtsev, VV, Tennikova, TB, Belnikevich, NG, Belenkii, BG, Frenkel, SY & Koton, MM 1987, 'Effect of draining of macromolecules on the results of size-exclusion chromatography measurements', Chromatographia, Том. 24, № 1, стр. 633-636. https://doi.org/10.1007/BF02688557

APA

Vilenchik, L. Z., Zhmakina, T. P., Sklizkova, V. P., Kudriavtsev, V. V., Tennikova, T. B., Belnikevich, N. G., Belenkii, B. G., Frenkel, S. Y., & Koton, M. M. (1987). Effect of draining of macromolecules on the results of size-exclusion chromatography measurements. Chromatographia, 24(1), 633-636. https://doi.org/10.1007/BF02688557

Vancouver

Vilenchik LZ, Zhmakina TP, Sklizkova VP, Kudriavtsev VV, Tennikova TB, Belnikevich NG и пр. Effect of draining of macromolecules on the results of size-exclusion chromatography measurements. Chromatographia. 1987 Дек.;24(1):633-636. https://doi.org/10.1007/BF02688557

Author

Vilenchik, L. Z. ; Zhmakina, T. P. ; Sklizkova, V. P. ; Kudriavtsev, V. V. ; Tennikova, T. B. ; Belnikevich, N. G. ; Belenkii, B. G. ; Frenkel, S. Ya ; Koton, M. M. / Effect of draining of macromolecules on the results of size-exclusion chromatography measurements. в: Chromatographia. 1987 ; Том 24, № 1. стр. 633-636.

BibTeX

@article{06e4bfbeadb14a81a66e832bc135c89b,
title = "Effect of draining of macromolecules on the results of size-exclusion chromatography measurements",
abstract = "Using chromatographic analysis and viscometric investigations of polyamic acids, it has been shown that the linear relationship of the logarithm of intrinsic viscosity and the logarithm of molecular weight of flexible-chain macromolecules exhibits a break on passing from the oligomeric to the polymeric range. Simultaneously, the Huggins constant also changes. These changes result from a decrease in the draining of macromolecules with increasing number of statistical segments. In particular, draining affects the hydrodynamic dimensions determining the SEC-behavior of macromolecules. Semi-empirical expressions have been obtained for the Flory constant Φ and the constants in the Mark-Kuhn-Houwink equation as functions of the draining of macromolecules, the number of their statistical segments and the parameter of volume interaction characterizing the thermodynamic strength of solvent. For this purpose the solution of an integral equation for eigen-functions in the Zimm theory found by Tschoegl was applied.",
keywords = "Draining, Macromolecules, Polymers, Size-exclusion chromatography",
author = "Vilenchik, {L. Z.} and Zhmakina, {T. P.} and Sklizkova, {V. P.} and Kudriavtsev, {V. V.} and Tennikova, {T. B.} and Belnikevich, {N. G.} and Belenkii, {B. G.} and Frenkel, {S. Ya} and Koton, {M. M.}",
year = "1987",
month = dec,
doi = "10.1007/BF02688557",
language = "English",
volume = "24",
pages = "633--636",
journal = "Chromatographia",
issn = "0009-5893",
publisher = "Springer Nature",
number = "1",

}

RIS

TY - JOUR

T1 - Effect of draining of macromolecules on the results of size-exclusion chromatography measurements

AU - Vilenchik, L. Z.

AU - Zhmakina, T. P.

AU - Sklizkova, V. P.

AU - Kudriavtsev, V. V.

AU - Tennikova, T. B.

AU - Belnikevich, N. G.

AU - Belenkii, B. G.

AU - Frenkel, S. Ya

AU - Koton, M. M.

PY - 1987/12

Y1 - 1987/12

N2 - Using chromatographic analysis and viscometric investigations of polyamic acids, it has been shown that the linear relationship of the logarithm of intrinsic viscosity and the logarithm of molecular weight of flexible-chain macromolecules exhibits a break on passing from the oligomeric to the polymeric range. Simultaneously, the Huggins constant also changes. These changes result from a decrease in the draining of macromolecules with increasing number of statistical segments. In particular, draining affects the hydrodynamic dimensions determining the SEC-behavior of macromolecules. Semi-empirical expressions have been obtained for the Flory constant Φ and the constants in the Mark-Kuhn-Houwink equation as functions of the draining of macromolecules, the number of their statistical segments and the parameter of volume interaction characterizing the thermodynamic strength of solvent. For this purpose the solution of an integral equation for eigen-functions in the Zimm theory found by Tschoegl was applied.

AB - Using chromatographic analysis and viscometric investigations of polyamic acids, it has been shown that the linear relationship of the logarithm of intrinsic viscosity and the logarithm of molecular weight of flexible-chain macromolecules exhibits a break on passing from the oligomeric to the polymeric range. Simultaneously, the Huggins constant also changes. These changes result from a decrease in the draining of macromolecules with increasing number of statistical segments. In particular, draining affects the hydrodynamic dimensions determining the SEC-behavior of macromolecules. Semi-empirical expressions have been obtained for the Flory constant Φ and the constants in the Mark-Kuhn-Houwink equation as functions of the draining of macromolecules, the number of their statistical segments and the parameter of volume interaction characterizing the thermodynamic strength of solvent. For this purpose the solution of an integral equation for eigen-functions in the Zimm theory found by Tschoegl was applied.

KW - Draining

KW - Macromolecules

KW - Polymers

KW - Size-exclusion chromatography

UR - http://www.scopus.com/inward/record.url?scp=0343842451&partnerID=8YFLogxK

U2 - 10.1007/BF02688557

DO - 10.1007/BF02688557

M3 - Article

AN - SCOPUS:0343842451

VL - 24

SP - 633

EP - 636

JO - Chromatographia

JF - Chromatographia

SN - 0009-5893

IS - 1

ER -

ID: 87868002