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Dynamic properties of adsorption layers of heptadecafluoro-1-nonanol. Effect of surface phase transitions. / Noskov, Boris A.; Akentiev, Alexander V.; Lin, Shi Yow.

в: Journal of Molecular Liquids, Том 282, 15.05.2019, стр. 316-322.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{d2154604e25a432ab89701e9b088ac9c,
title = "Dynamic properties of adsorption layers of heptadecafluoro-1-nonanol. Effect of surface phase transitions",
abstract = "The dilational surface rheology was applied to study the properties of adsorbed layers of a fluorinated surfactant (heptadecafluoro-1-nonanol) with a surface phase transition at the water – air interface. At relatively low surface tensions (<~57 mN/m) the dynamic surface elasticity reached anomalously high values (~200 mN/m) and exhibited a local minimum at higher surface tensions in the region of a two-dimensional phase transition. A mathematical model was developed to describe dilational properties of the adsorbed layer in the region of coexistence of two surface phases. The application of this model to solutions of the fluorinated surfactant allowed estimation of the kinetic parameters of the relaxation processes in the surface layer.",
keywords = "Dilational surface rheology, Fluorinated surfactants, Gibbs monolayers, Phase transitions",
author = "Noskov, {Boris A.} and Akentiev, {Alexander V.} and Lin, {Shi Yow}",
year = "2019",
month = may,
day = "15",
doi = "10.1016/j.molliq.2019.03.009",
language = "English",
volume = "282",
pages = "316--322",
journal = "Journal of Molecular Liquids",
issn = "0167-7322",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Dynamic properties of adsorption layers of heptadecafluoro-1-nonanol. Effect of surface phase transitions

AU - Noskov, Boris A.

AU - Akentiev, Alexander V.

AU - Lin, Shi Yow

PY - 2019/5/15

Y1 - 2019/5/15

N2 - The dilational surface rheology was applied to study the properties of adsorbed layers of a fluorinated surfactant (heptadecafluoro-1-nonanol) with a surface phase transition at the water – air interface. At relatively low surface tensions (<~57 mN/m) the dynamic surface elasticity reached anomalously high values (~200 mN/m) and exhibited a local minimum at higher surface tensions in the region of a two-dimensional phase transition. A mathematical model was developed to describe dilational properties of the adsorbed layer in the region of coexistence of two surface phases. The application of this model to solutions of the fluorinated surfactant allowed estimation of the kinetic parameters of the relaxation processes in the surface layer.

AB - The dilational surface rheology was applied to study the properties of adsorbed layers of a fluorinated surfactant (heptadecafluoro-1-nonanol) with a surface phase transition at the water – air interface. At relatively low surface tensions (<~57 mN/m) the dynamic surface elasticity reached anomalously high values (~200 mN/m) and exhibited a local minimum at higher surface tensions in the region of a two-dimensional phase transition. A mathematical model was developed to describe dilational properties of the adsorbed layer in the region of coexistence of two surface phases. The application of this model to solutions of the fluorinated surfactant allowed estimation of the kinetic parameters of the relaxation processes in the surface layer.

KW - Dilational surface rheology

KW - Fluorinated surfactants

KW - Gibbs monolayers

KW - Phase transitions

UR - http://www.scopus.com/inward/record.url?scp=85062856090&partnerID=8YFLogxK

U2 - 10.1016/j.molliq.2019.03.009

DO - 10.1016/j.molliq.2019.03.009

M3 - Article

AN - SCOPUS:85062856090

VL - 282

SP - 316

EP - 322

JO - Journal of Molecular Liquids

JF - Journal of Molecular Liquids

SN - 0167-7322

ER -

ID: 42838704