Результаты исследований: Научные публикации в периодических изданиях › статья
Does [TcF(CO)5] exist? the crystal and molecular structure of [Tc(CO)3(OH)0.49F0.51]4·[Tc(CO)5(BF4)]. / Stepanova, E.S.; Gurzhiy, V.V.; Tyupina, M.Yu.; Miroslavov, A.E.; Sidorenko, G.V.; Lumpov, A.A.
в: Dalton Transactions, Том 45, № 20, 2016, стр. 8428-8432.Результаты исследований: Научные публикации в периодических изданиях › статья
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TY - JOUR
T1 - Does [TcF(CO)5] exist? the crystal and molecular structure of [Tc(CO)3(OH)0.49F0.51]4·[Tc(CO)5(BF4)]
AU - Stepanova, E.S.
AU - Gurzhiy, V.V.
AU - Tyupina, M.Yu.
AU - Miroslavov, A.E.
AU - Sidorenko, G.V.
AU - Lumpov, A.A.
PY - 2016
Y1 - 2016
N2 - © 2016 The Royal Society of Chemistry. Technetium pentacarbonyl fluoride [TcF(CO)5] was prepared for the first time by reaction of [TcI(CO)5] with solid AgF in a dichloromethane solution at -23 °C. Low temperature crystallization of the resulting compound in a glass vial yielded an unusual complex [Tc(CO)3(OH)0.49F0.51]4·[Tc(CO)5(BF4)] characterized by single crystal XRD.
AB - © 2016 The Royal Society of Chemistry. Technetium pentacarbonyl fluoride [TcF(CO)5] was prepared for the first time by reaction of [TcI(CO)5] with solid AgF in a dichloromethane solution at -23 °C. Low temperature crystallization of the resulting compound in a glass vial yielded an unusual complex [Tc(CO)3(OH)0.49F0.51]4·[Tc(CO)5(BF4)] characterized by single crystal XRD.
U2 - 10.1039/c6dt00958a
DO - 10.1039/c6dt00958a
M3 - Article
VL - 45
SP - 8428
EP - 8432
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 20
ER -
ID: 7927508